1,2,3-Triaminobenzene dihydrochloride

Base Information

• Chemical Name: 1,2,3-Triaminobenzene dihydrochloride
• CAS No.: 66046-54-6
• Molecular Formula: C₆H₉N₃*2ClH
• Molecular Weight: 196.079
• European Community (EC) Number: 622-122-9
• UNII: DQ3YR4PD34
• Mol file: 66046-54-6.mol

Synonyms:66046-54-6;1,2,3-TRIAMINOBENZENE DIHYDROCHLORIDE;1,2,3-Benzenetriamine, dihydrochloride;Benzene-1,2,3-triamine dihydrochloride;DQ3YR4PD34;1,2,3-Benzenetriamine, hydrochloride (1:2);UNII-DQ3YR4PD34;SCHEMBL9700979;AKOS024340554;benzene-1,2,3-triamine;dihydrochloride

Chemical Property of 1,2,3-Triaminobenzene dihydrochloride

Chemical Property:

• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 195.0330028
• Heavy Atom Count: 11
• Complexity: 84.3

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C(=C1)N)N)N.Cl.Cl

Technology Process of 1,2,3-Triaminobenzene dihydrochloride

There total 1 articles about 1,2,3-Triaminobenzene dihydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

2,6-dinitroaniline (606-22-4) → 1,2,3-triaminobenzene dihydrochloride (66046-54-6,137959-71-8)

Guidance literature:

With hydrogenchloride; hydrogen; palladium on activated charcoal; In methanol; at 50 ℃; for 4h; under 45603.1 Torr;

DOI:10.1007/s11172-007-0184-z

Reference yield: 97.0%

1,2,3-triaminobenzene dihydrochloride (66046-54-6,137959-71-8) → 4-amino-2,1,3-benzoselenadiazole (767-65-7)

Guidance literature:

1,2,3-triaminobenzene dihydrochloride; With selenium(IV) oxide; In ethanol; water; at 20 ℃;

With sodium hydroxide; In ethanol; water; Cooling with ice;

DOI:10.1016/j.tet.2010.08.044

Reference yield: 78.0%

formic acid (64-18-6) + 1,2,3-triaminobenzene dihydrochloride (66046-54-6,137959-71-8) → C8H7N3O (137654-47-8)

Guidance literature:

In water; for 2.5h; Heating;

DOI:10.1007/s11172-007-0184-z

upstream raw materials:

2,6-dinitroaniline

Downstream raw materials:

4-aminobenzimidazole

quinoxalin-5-ylamine

N,N',N''-benzene-1,2,3-triyl-tris-acetamide

N-acetyl-sulfanilic acid quinoxalin-5-ylamide

Refernces

• 1、 Elkin,Tolkacheva,Chernysheva,Karmanova,Konyushkin,Semenov. "Hydrogenation on palladium-containing granulated catalysts 3. Synthesis of aminobenzimidazoles by catalytic hydrogenation of dinitroanilines". . p. 1216 - 1226. Retrieved 2008/09/19.