1-Phenyl-1,2-propanedione-2-oxime

Base Information

Chemical Name:1-Phenyl-1,2-propanedione-2-oxime
CAS No.:119-51-7
Molecular Formula:C9H9NO2
Molecular Weight:163.176
Hs Code.:29280090
European Community (EC) Number:204-329-2
NSC Number:5410
DSSTox Substance ID:DTXSID5051602
Mol file:119-51-7.mol

Synonyms:1-phenyl-1,2-propanedione-2-oxime;alpha-isonitropropiophenone

Suppliers and Price of 1-Phenyl-1,2-propanedione-2-oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-Phenyl-1,2-propanedione-2-oxime
2.5g
$ 75.00

TCI Chemical
2-Isonitrosopropiophenone >98.0%(GC)
25g
$ 61.00

Sigma-Aldrich
α-Isonitrosopropiophenone
10g
$ 28.80

Sigma-Aldrich
α-Isonitrosopropiophenone
50g
$ 132.00

Frontier Specialty Chemicals
1-Phenyl-1,2-propanedione-2-oxime 99%
25g
$ 77.00

Crysdot
2-(Hydroxyimino)-1-phenylpropan-1-one 95+%
500g
$ 512.00

Apolloscientific
1-Phenyl-1,2-propanedione-2-oxime
25g
$ 203.00

Apolloscientific
1-Phenyl-1,2-propanedione-2-oxime
5g
$ 115.00

American Custom Chemicals Corporation
1-PHENYL-1,2-PROPANEDIONE-2-OXIME 95.00%
25G
$ 1156.72

Alichem
2-(Hydroxyimino)-1-phenylpropan-1-one
500g
$ 563.20

Total 59 raw suppliers

Chemical Property of 1-Phenyl-1,2-propanedione-2-oxime

Chemical Property:

Appearance/Colour:White to light yellow crystals
Vapor Pressure:0.000835mmHg at 25°C
Melting Point:113-115 °C(lit.)
Refractive Index:1.537
Boiling Point:292.5 °C at 760 mmHg
PKA:9.28±0.10(Predicted)
Flash Point:130.7 °C
PSA：49.66000
Density:1.1 g/cm³
LogP:1.71940
Storage Temp.:2-8°C
Solubility.:soluble in Methanol
XLogP3:2.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:163.063328530
Heavy Atom Count:12
Complexity:193

Purity/Quality:

99%, ^*data from raw suppliers

1-Phenyl-1,2-propanedione-2-oxime ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22-36/37/38
Safety Statements: 24/25-37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC(=NO)C(=O)C1=CC=CC=C1
Isomeric SMILES:C/C(=N\O)/C(=O)C1=CC=CC=C1
Uses Reactant involved in synthesis of:Cyclometalated iridium complexes for photophysical and electrochemical studiesHydroimidazothiazoles via iodination and cyclization reactionsReactant involved in:Sonogashira coupling reactionsAllylation of aromatic aldehydes using imidazole oside catalystsBeckmann rearrangement of α-oximinoketonesReagent used in the colorimetric determination of urea

Technology Process of 1-Phenyl-1,2-propanedione-2-oxime

There total 20 articles about 1-Phenyl-1,2-propanedione-2-oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 93-55-0
1-phenyl-propan-1-one

: 119-51-7
1-phenyl-1,2-propanedione 2-oxime

Guidance literature:: With hydrogenchloride; tert-Butyl thionitrate; In tetrahydrofuran; at 0 ℃; for 0.3h;
DOI:10.1016/S0040-4039(00)99137-8

Reference yield: 93.0%

: 768-03-6,26742-84-7
Phenyl vinyl ketone

: 119-51-7
1-phenyl-1,2-propanedione 2-oxime

Guidance literature:: With n-Butyl nitrite; phenylsilane; N,N'-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II) complex; In tetrahydrofuran; for 19h; Ambient temperature;
DOI:10.1246/bcsj.64.2948