Dimethylbis[(1-phenylethenyl)oxy]silane

Base Information

• Chemical Name: Dimethylbis[(1-phenylethenyl)oxy]silane
• CAS No.: 6651-32-7
• Molecular Formula: C18H20O2Si
• Molecular Weight: 296.441
• DSSTox Substance ID: DTXSID30546648
• Wikidata: Q82424545
• Mol file: 6651-32-7.mol

Synonyms:6651-32-7;Dimethylbis[(1-phenylethenyl)oxy]silane;SCHEMBL11224354;DTXSID30546648

Chemical Property of Dimethylbis[(1-phenylethenyl)oxy]silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 296.123256411
• Heavy Atom Count: 21
• Complexity: 329

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(OC(=C)C1=CC=CC=C1)OC(=C)C2=CC=CC=C2

Technology Process of Dimethylbis[(1-phenylethenyl)oxy]silane

There total 3 articles about Dimethylbis[(1-phenylethenyl)oxy]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dimethylsilicon dichloride (75-78-5,30107-43-8) + acetophenone (98-86-2) → dimethylbis((1-phenylvinyl)oxy)silane (6651-32-7)

Guidance literature:

With triethylamine; sodium iodide; In acetonitrile; for 1.75h;

DOI:10.1080/00397919108021281

Reference yield: 35.0%

dimethylsilicon dichloride (75-78-5,30107-43-8) + 1-phenyl-propan-1-one (93-55-0) → dimethylbis((1-phenylvinyl)oxy)silane (6651-32-7)

Guidance literature:

With 2,2,6,6-tetramethylpiperidinyl-lithium; In tetrahydrofuran; for 0.5h;

DOI:10.1016/S0040-4039(00)84912-6

Reference yield:

→ dimethylbis((1-phenylvinyl)oxy)silane (6651-32-7)

Guidance literature:

DOI:10.1016/S0022-328X(00)94483-8

upstream raw materials:

dimethylsilicon dichloride

acetophenone

1-phenyl-propan-1-one

Downstream raw materials:

phenacylacetophenone