Boranediamine, N,N,N',N'-tetraethyl-1-[(1-phenylethenyl)oxy]-

Base Information

• Chemical Name: Boranediamine, N,N,N',N'-tetraethyl-1-[(1-phenylethenyl)oxy]-
• CAS No.: 666736-25-0
• Molecular Formula: C16H27BN2O
• Molecular Weight: 274.214
• DSSTox Substance ID: DTXSID10458831
• Nikkaji Number: J1.959.615J
• Wikidata: Q82282371
• Mol file: 666736-25-0.mol

Synonyms:Boranediamine, N,N,N',N'-tetraethyl-1-[(1-phenylethenyl)oxy]-;666736-25-0;DTXSID10458831;alpha-[Bis(diethylamino)boryloxy]styrene

Chemical Property of Boranediamine, N,N,N',N'-tetraethyl-1-[(1-phenylethenyl)oxy]-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 274.2216437
• Heavy Atom Count: 20
• Complexity: 260

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: B(N(CC)CC)(N(CC)CC)OC(=C)C1=CC=CC=C1

Technology Process of Boranediamine, N,N,N',N'-tetraethyl-1-[(1-phenylethenyl)oxy]-

There total 1 articles about Boranediamine, N,N,N',N'-tetraethyl-1-[(1-phenylethenyl)oxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

bis(diethylamino)boron chloride (868-25-7) + acetophenone (98-86-2) → 1-(1-bis(diethylamino)boryloxyvinyl)benzene (666736-25-0)

Guidance literature:

With potassium hexamethyldisilazane; In tetrahydrofuran; byproducts: KCl; under Ar atm. to soln. KHDMS in THF ketone in THF was added dropwise at 0°C for 30 min, soln. chlorobis(dialkylamino)borane in THF was added and stirred at room temp. for 1 h; soln. was cenrifugated, ppt. was filtered, volatiles were removed in vacuo;

DOI:10.1021/om700676w

Reference yield: 86.0%

glyoxylic acid ethyl ester (924-44-7) + 1-(1-bis(diethylamino)boryloxyvinyl)benzene (666736-25-0) → ethyl 2-(diethylamino)-4-oxo-4-phenylbutanoate

Guidance literature:

In N,N-dimethyl-formamide; at 50 ℃;

DOI:10.1021/ol0497436

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1-(1-bis(diethylamino)boryloxyvinyl)benzene (666736-25-0) → 3-(diethylamino)-1-phenylpropan-1-one

Guidance literature:

In N,N-dimethyl-formamide; at 50 ℃;

DOI:10.1021/ol0497436

upstream raw materials:

bis(diethylamino)boron chloride

acetophenone

Downstream raw materials:

3-diethylamino-1,3-diphenyl-propan-1-one