[1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl-

Base Information Edit

Chemical Name:[1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl-
CAS No.:2417-04-1
Deprecated CAS:2353429-73-7
Molecular Formula:C16H18O2
Molecular Weight:242.318
Hs Code.:2907299090
European Community (EC) Number:607-334-1
NSC Number:128399,93821
UNII:KV93XB4DEU
DSSTox Substance ID:DTXSID5062396
Nikkaji Number:J107.312E
Wikidata:Q72507511
ChEMBL ID:CHEMBL449983
Mol file:2417-04-1.mol

Synonyms:2417-04-1;2,2',6,6'-tetramethyl-4,4'-biphenol;3,3',5,5'-tetramethylbiphenyl-4,4'-diol;4-(4-hydroxy-3,5-dimethylphenyl)-2,6-dimethylphenol;[1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl-;2,2',6,6'-Tetramethyl-p,p'-biphenol;di(2,6-dimethylphenol);KV93XB4DEU;CHEMBL449983;MFCD00094737;NSC-93821;NSC-128399;3,3',5,5'-tetramethyl-(1,1'-biphenyl)-4,4'-diol;3,3',5,5'-tetramethyl-[1,1'-biphenyl]-4,4'-diol;3,3',5,5'-Tetramethyl-4-4'-dihydroxybiphenyl;3,3,5,5-Tetramethyl [1,1'-biphenyl] 4,4'-diol;3,3',5,5'-tetramethyl[1,1'-biphenyl]-4,4'-diol;(1,1'-Biphenyl)-4,4'-diol, 3,3',5,5'-tetramethyl-;3,3',5,5'-Tetramethyl(1,1'-biphenyl)-4,4'-diol;3,3,5,5-Tetramethylbiphenyl-4,4-diol;NSC93821;TM-BPL;UNII-KV93XB4DEU;4,4'-dihydroxy-3,3',5,5'-tetramethyl-biphenyl;SCHEMBL220910;DTXSID5062396;4,4'-Bi(2,6-dimethylphenol);CAA41704;BDBM50266964;NSC 93821;NSC128399;2,2,6,6-Tetramethyl-4,4-biphenol;AKOS015912834;NSC 128399;AC-14423;SY052537;CS-0153719;FT-0634257;T3145;4,4'-dihydroxy-3,3',5,5'-tetramethylbiphenyl;EN300-6513087;J-015381;3,3',5,5'-tetramethyl-1,1'-biphenyl-4,4'-diol;Z3234902406;4-(3,5-DIMETHYL-4-OXIDANYL-PHENYL)-2,6-DIMETHYL-PHENOL;3,3 inverted exclamation mark ,5,5 inverted exclamation mark -Tetramethylbiphenyl-4,4 inverted exclamation mark -diol

Suppliers and Price of [1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl-

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3,3'',5,5''-Tetramethyl[1,1''-biphenyl]-4,4''-diol
5g
$ 105.00

TCI Chemical
3,3',5,5'-Tetramethylbiphenyl-4,4'-diol >98.0%(GC)
25g
$ 387.00

TCI Chemical
3,3',5,5'-Tetramethylbiphenyl-4,4'-diol >98.0%(GC)
5g
$ 109.00

Sigma-Aldrich
3,3',5,5'-TETRAMETHYL[1,1'-BIPHENYL]-4,4'-DIOL AldrichCPR
5mg
$ 115.00

Labseeker
3,3',5,5'-tetramethyl-4,4'-diallyloxybiphenyl 95
1kg
$ 377.00

Crysdot
3,3',5,5'-Tetramethyl-[1,1'-biphenyl]-4,4'-diol 97%
10g
$ 46.00

Crysdot
3,3',5,5'-Tetramethyl-[1,1'-biphenyl]-4,4'-diol 97%
5g
$ 35.00

Crysdot
3,3',5,5'-Tetramethyl-[1,1'-biphenyl]-4,4'-diol 97%
25g
$ 72.00

Crysdot
3,3',5,5'-Tetramethyl-[1,1'-biphenyl]-4,4'-diol 97%
100g
$ 205.00

American Custom Chemicals Corporation
2,2',6,6'-TETRAMETHYL-4,4'-BIPHENOL 95.00%
25G
$ 1032.10

Total 62 raw suppliers

Chemical Property of [1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl- Edit

Chemical Property:

Appearance/Colour:Light yellow powder
Melting Point:222-225 °C(lit.)
Refractive Index:1.6000 (estimate)
Boiling Point:354.6 °C at 760 mmHg
PKA:10.22±0.40(Predicted)
Flash Point:162.4 °C
PSA：40.46000
Density:1.118 g/cm³
LogP:3.99840
Storage Temp.:Sealed in dry,Room Temperature
Solubility.:DMSO (Slightly), Methanol (Slightly)
XLogP3:4.3
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:242.130679813
Heavy Atom Count:18
Complexity:226

Purity/Quality:

Purity greater than 99.5% ^*data from raw suppliers

3,3'',5,5''-Tetramethyl[1,1''-biphenyl]-4,4''-diol ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi,Xn
Hazard Codes:Xi,Xn
Statements: 36/37/38-40
Safety Statements: 26-36-22

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=CC(=C1O)C)C2=CC(=C(C(=C2)C)O)C
Uses 2,2',6,6'-tetramethyl-4,4'-biphenol is used for the synthesis of liquid crystal polymer, the synthetic polymer material having a high strength, high modulus, excellent dimensional stability and used widely in various fields. 3,3'',5,5''-Tetramethyl[1,1''-biphenyl]-4,4''-diol, is a building block used in chemical synthesis of Mexiletine (M340800) and it’s derivatives.

Technology Process of [1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl-

There total 41 articles about [1,1'-Biphenyl]-4,4'-diol, 3,3',5,5'-tetramethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 576-26-1,25134-01-4
2.6-dimethylphenol

: 2417-04-1,60133-38-2
3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl

Guidance literature:: 2.6-dimethylphenol; With oxygen; In tert-butyl alcohol; at 70 ℃; for 18h; under 760.051 Torr; Green chemistry;

With hydrogen; In tert-butyl alcohol; at 50 ℃; for 4h; under 760.051 Torr; Temperature; Solvent; Time; Catalytic behavior; Green chemistry;
DOI:10.1039/c7cy00919d

Reference yield: 99.0%

: 4906-22-3
3,3',5,5'-tetramethyldiphenoquinone

: 2417-04-1,60133-38-2
3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl

Guidance literature:: With hydrogen; In tert-butyl alcohol; at 50 ℃; for 4h; under 760.051 Torr; Reagent/catalyst; Catalytic behavior;
DOI:10.1039/c7cy00919d

Reference yield: 80.0%

: 527-60-6
Mesitol

: 527-61-7
2,6-dimethyl-1,4-benzoquinone

: 2417-04-1,60133-38-2
3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl

: 3,3',5,5'-tetramethyl-4,4'-diphenoquinone

Guidance literature:: With C₃₄H₂₄Cl₄Cu₂FeN₁₀O₄^(1-)*C₈H₂₀N⁽¹⁺⁾; oxygen; sodium hydroxide; In methanol; at 25 ℃; for 6h;
DOI:10.1002/ejic.201400066