1,1,2,2-Tetrafluoro-3-(vinyloxy)propane

Base Information

• Chemical Name: 1,1,2,2-Tetrafluoro-3-(vinyloxy)propane
• CAS No.: 29819-80-5
• Molecular Formula: C5H6 F4 O
• Molecular Weight: 158.096
• European Community (EC) Number: 249-879-4
• DSSTox Substance ID: DTXSID10183954
• Nikkaji Number: J107.311G
• Wikidata: Q81985497
• Mol file: 29819-80-5.mol

Synonyms:29819-80-5;1,1,2,2-Tetrafluoro-3-(vinyloxy)propane;3-ethenoxy-1,1,2,2-tetrafluoropropane;EINECS 249-879-4;Propane,3-(ethenyloxy)-1,1,2,2-tetrafluoro-;Vinyl 1H,1H,3H-perfluoropropyl ether;2,2,3,3-tetrafluoropropyl vinyl ether;SCHEMBL2465659;DTXSID10183954;2,2,3,3-Tetrafluoropropyloxyethene;MFCD22123992;2,2,3,3-tetrafluoropropan-1-ol vinyl ether

Chemical Property of 1,1,2,2-Tetrafluoro-3-(vinyloxy)propane

Chemical Property:

• Vapor Pressure: 64.6mmHg at 25°C
• Boiling Point: 90°Cat760mmHg
• Flash Point: 3.8°C
• PSA: 9.23000
• Density: 1.173g/cm³
• LogP: 2.04690
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 158.03547746
• Heavy Atom Count: 10
• Complexity: 112

Purity/Quality:

98%Min ^*data from raw suppliers

2,2,3,3-Tetrafluoropropyl vinyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=COCC(C(F)F)(F)F

Technology Process of 1,1,2,2-Tetrafluoro-3-(vinyloxy)propane

There total 1 articles about 1,1,2,2-Tetrafluoro-3-(vinyloxy)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

2,2,3,3-tetrafluoropropanol (76-37-9) + acetylene (74-86-2,25067-58-7) → 2,2,3,3-tetrafluoro-propan-1-ol vinyl ether (29819-80-5)

Guidance literature:

With cadmium(II) acetate; at 185 ℃; for 5h; Product distribution; various reagents(potassium alkoxides and hydroxide); various solvents, amount reagents, complexing additives, reaction time;

Reference yield: 97.0%

bis(2-phenethyl)phosphine (93017-30-2) + 2,2,3,3-tetrafluoro-propan-1-ol vinyl ether (29819-80-5) → 1-(2,2,3,3-tetrafluoropropoxy)ethyl bis(2-phenylethyl)phosphinodiselenoate

Guidance literature:

With selenium; In 1,4-dioxane; at 90 ℃; Inert atmosphere;

DOI:10.1055/s-0031-1289655

Reference yield: 60.0%

2,2,3,3-tetrafluoro-propan-1-ol vinyl ether (29819-80-5) + benzoic acid (65-85-0,8013-63-6) → 1-(2,2,3,3-tetrafluoropropoxy)ethyl benzoate

Guidance literature:

With trifluoroacetic acid; In benzene; at 55 - 65 ℃; for 3.5h;

DOI:10.1023/A:1019516520501

upstream raw materials:

2,2,3,3-tetrafluoropropanol

acetylene

Downstream raw materials:

1-[(2,2,3,3-tetrafluoropropyl)oxy]ethyl bis(4-chlorophenethyl)phosphinothioselenoate

1-[(2,2,3,3-tetrafluoropropyl)oxy]ethyl bis(4-chlorophenethyl)phosphinoselenothioate

Refernces

• 1、 Trofimov, B. A.,Khil'ko, M. Ya.,Nedolya, N. A.,Demanov, Yu. K.,Vyalykh, E. P.. "SYNTHESIS AND SOME PROPERTIES OF THE VINYL ETHERS OF POLYFLUORINATED ALCOHOLS". . p. 647 - 651. Retrieved 2007/10/02.