Manganese,decacarbonyl(mercury)di-, (2Hg-Mn)

Base Information

Chemical Name:Manganese,decacarbonyl(mercury)di-, (2Hg-Mn)
CAS No.:15525-07-2
Molecular Formula:C10Hg Mn2 O10
Molecular Weight:590.57
Hs Code.:

Synonyms:Manganese,decacarbonyl-m-mercuriodi-(8CI); Mercury pentacarbonylmanganate(-I) (7CI); Mercury, bis(pentacarbonylmanganio)-(8CI); Bis[pentacarbonylmanganese]mercury; Mercuriobis(pentacarbonylmanganese)

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Chemical Property of Manganese,decacarbonyl(mercury)di-, (2Hg-Mn)

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Technology Process of Manganese,decacarbonyl(mercury)di-, (2Hg-Mn)

There total 2 articles about Manganese,decacarbonyl(mercury)di-, (2Hg-Mn) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 13859-41-1
sodium pentacarbonyl manganate

: 59993-37-2
(1,7-dicarba-closo-dodecaboran⁽¹²⁾-yl-1)mercury chloride

: 10170-69-1
dimanganese decacarbonyl

: 64147-82-6
bis(1,7-dicarba-closo-dodecaboran⁽¹²⁾-yl-1)mercury

: 15525-07-2
{Mn(CO)5}2Hg

Guidance literature:: In tetrahydrofuran; a soln. of the borane in THF is added dropwise at -20°C to a soln. of NaMn(CO)5 in THF, stirred for 2 h at this temp., stirred for 1 h at 20°C, left to stand for 16 h; the soln. is decanted from the ppt., the solvent is evapd.,, Hg(Mn(CO)5)2 is obtained by crystn. from benzene-THF, the mother liquor is evapd., the residue is chromd.;
DOI:10.1007/BF00698452

Reference yield:

: 14100-30-2
pentacarbonylchloromanganese(I)

: 587-85-9,1337-09-3
diphenylmercury(II)

: 15525-07-2
{Mn(CO)5}2Hg

: 100-56-1
phenylmercury(II) chloride

Guidance literature:: In toluene; byproducts: benzene, benzophenone; under Ar; refluxing a soln. of the Mn-complex and excess (C6H5)2Hg (1:2) for 1.25 h; filtn. from Hg, distn. of the toluene in vac. from filtrate, column chromy. (SiO2, cyclohexane/benzene) of the residue;

Reference yield: 90.0%

: 15525-07-2
{Mn(CO)5}2Hg

: Hg(PtC₆Cl₅(P(C₆H₅)3)2)2

: 110657-62-0
(CO)5MnHgPtC₆Cl₅(P(C₆H₅)3)2

Guidance literature:: In toluene; refluxed for 2 h; cooled, solvent removed in vacuo, recrystd. (benzene-hexane); elem. anal.;
DOI:10.1039/DT9860001011