2-Cyclohexene-1,4-dicarboxylic acid

Base Information

• Chemical Name: 2-Cyclohexene-1,4-dicarboxylic acid
• CAS No.: 19618-93-0
• Molecular Formula: C8H10O4
• Molecular Weight: 170.165
• Hs Code.: 2917209090
• Mol file: 19618-93-0.mol

Synonyms:2-Cyclohexene-1,4-dicarboxylic acid;trans-Cyclohex-2-en-1,4-dicarbonsaeure;

Chemical Property of 2-Cyclohexene-1,4-dicarboxylic acid

Chemical Property:

• Vapor Pressure: 4.99E-07mmHg at 25°C
• Boiling Point: 386°C at 760 mmHg
• Flash Point: 201.4°C
• PSA: 74.60000
• Density: 1.369g/cm³
• LogP: 0.73800

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Cyclohexene-1,4-dicarboxylic acid

There total 20 articles about 2-Cyclohexene-1,4-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

carbon dioxide (124-38-9,18923-20-1) + cyclohexa-1,3-diene (1165952-91-9) → 2-cyclohexene-1,4-dicarboxylic acid (19618-93-0)

Guidance literature:

With tetrabutylammomium bromide; In N,N-dimethyl-formamide; under 3750.38 Torr; Pressure; Electrochemical reaction;

DOI:10.1039/c3ra00129f

Reference yield: 75.0%

(2Z,4E)-2,4-hexadienedioic acid (1119-73-9) + ethene (74-85-1) → 2-cyclohexene-1,4-dicarboxylic acid (19618-93-0)

Guidance literature:

With iodine; In tetrahydrofuran; at 160 ℃; for 25h; under 13032.5 Torr;

Reference yield: 70.0%

carbon dioxide (124-38-9,18923-20-1) + cyclohexene (110-83-8) → 2-cyclohexene-1,4-dicarboxylic acid (19618-93-0)

Guidance literature:

carbon dioxide; cyclohexene; With tetrabutylammomium bromide; In N,N-dimethyl-formamide; at 20 ℃; under 22502.3 Torr; Electrochemical reaction; Nickel cathode/platinum anode-equipped high-pressure undivided electrochemical cell;

In water; regioselective reaction; Acidic conditions;

DOI:10.1016/j.electacta.2010.06.057

upstream raw materials:

ethene

trans,trans-muconic acid

(2Z,4E)-2,4-hexadienedioic acid

carbon dioxide

Downstream raw materials:

succinic acid

cyclohexa-1,3-diene-1,4-dicarboxylic acid

dimethyl 1,3-cyclohexadiene-1,4-dicarboxylate

dimethyl 1,4-cyclohexanedicarboxylate