Technology Process of 3H-Diazirine, 3-[3,5-bis(bromomethyl)phenyl]-3-(trifluoromethyl)-
There total 6 articles about 3H-Diazirine, 3-[3,5-bis(bromomethyl)phenyl]-3-(trifluoromethyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
N-Bromosuccinimide; dibenzoyl peroxide;
In
Methyl formate;
Heating;
irradiation;
DOI:10.1039/b303425a
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: n-BuLi / diethyl ether / 2.5 h / -30 - 0 °C
1.2: 91 percent / diethyl ether / 3 h / -50 °C
2.1: 213 mg / NH2OH / ethanol / 22 h / Heating
3.1: 88 percent / pyridine / 3 h / Heating
4.1: 97 percent / NH3 / diethyl ether / 8 h / -60 °C
5.1: 51 percent / N-bromosuccinimide; (PhCOO)2 / methyl formate / Heating; irradiation
6.1: 64 percent / N-bromosuccinimide; (PhCOO)2 / methyl formate / Heating; irradiation
With
pyridine; N-Bromosuccinimide; n-butyllithium; ammonia; hydroxylamine; dibenzoyl peroxide;
In
diethyl ether; ethanol; Methyl formate;
DOI:10.1039/b303425a
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 213 mg / NH2OH / ethanol / 22 h / Heating
2: 88 percent / pyridine / 3 h / Heating
3: 97 percent / NH3 / diethyl ether / 8 h / -60 °C
4: 51 percent / N-bromosuccinimide; (PhCOO)2 / methyl formate / Heating; irradiation
5: 64 percent / N-bromosuccinimide; (PhCOO)2 / methyl formate / Heating; irradiation
With
pyridine; N-Bromosuccinimide; ammonia; hydroxylamine; dibenzoyl peroxide;
In
diethyl ether; ethanol; Methyl formate;
DOI:10.1039/b303425a
