Tetrabutylammonium mu-hydrohexahydrodiborate

Base Information

• Chemical Name: Tetrabutylammonium mu-hydrohexahydrodiborate
• CAS No.: 40001-25-0
• Molecular Formula: C16H36N.B2H7
• Molecular Weight: 271.146
• Mol file: 40001-25-0.mol

Synonyms:Tetrabutylammonium mu-hydrohexahydrodiborate;

Chemical Property of Tetrabutylammonium mu-hydrohexahydrodiborate

Chemical Property:

• PSA: 0.00000
• LogP: 2.10040

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tetrabutylammonium mu-hydrohexahydrodiborate

There total 5 articles about Tetrabutylammonium mu-hydrohexahydrodiborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrabutylammonium borohydride → tetrabutylammonium diborohydride (40001-25-0)

Guidance literature:

With aluminium trichloride; In tetrahydrofuran; addn. of AlCl3 to Bu4NBH4 (molar ratio B:Al=4:1 to 2:1); not isolated, detd. by (11)B-NMR spectrocopy;

Reference yield:

(cyclopentadienyl)2Zr((μ-H)2-tetrahydroborate)2 + tetrabutylammonium borohydride → zirconocene hydride borohydride + tetrabutylammonium diborohydride (40001-25-0)

Guidance literature:

In benzene; not isolated;

DOI:10.1007/BF00949005

Reference yield:

aluminium trichloride (7446-70-0) + tetrabutylammonium borohydride → hydridoaluminium bis(tetrahydroborate) + tetrabutylammonium diborohydride (40001-25-0)

Guidance literature:

In diethylene glycol dimethyl ether; byproducts: Bu4NAl(BH4)nCl4-n; addn. of AlCl3 to Bu4NBH4 (molar ratio B:Al=1:1); not isolated, detd. by (11)B-NMR spectrocopy;

upstream raw materials:

aluminium trichloride

aluminium bromide