Phosphorous nitride

Base Information

• Chemical Name: Phosphorous nitride
• CAS No.: 17739-47-8
• Deprecated CAS: 2304530-09-2,2374853-78-6
• Molecular Formula: NP
• Molecular Weight: 44.9805
• European Community (EC) Number: 258-263-4
• DSSTox Substance ID: DTXSID9066255
• Wikipedia: Phosphorus_mononitride
• Wikidata: Q25323782
• Mol file: 17739-47-8.mol

Synonyms:Phosphorous nitride;azanylidynephosphane;17739-47-8;EINECS 258-263-4;52934-12-0;Phosphorus pentanitr;Phosphorus pentanitride;Phosphorus nitride (PN);DTXSID9066255;AKOS015909600;FT-0688074;FT-0693759

Chemical Property of Phosphorous nitride

Chemical Property:

• Melting Point: decomposes at 800℃ [HAW93]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: g/cm³
• LogP: 0.87628
• Water Solubility.: insoluble cold H2O, decomposed by hot H2O (HAW93]; soluble in common organic solvents [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 44.976836002
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N#P

Technology Process of Phosphorous nitride

There total 18 articles about Phosphorous nitride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

phosphorous (12185-10-3) + nitrogen (7727-37-9) → phosphorus nitride (17739-47-8)

Guidance literature:

In neat (no solvent); equilibrium at 1600°C and 10E-2 atm;;

Reference yield:

phosphorus (12185-09-0) + nitrogen (7727-37-9) → phosphorus nitride (17739-47-8)

Guidance literature:

In neat (no solvent); heating a equimolar mixt. of P2 and N2 in a closed tube by a tungsten wire; react. starts at 1500°C; complete react. after 2 h at 1800°C;; pptn. under polymerisation;;

Reference yield:

phosphorus → phosphorus nitride (17739-47-8)

Guidance literature:

With nitrogen; equilibrum at 900°C, 0.7-1 atm;

DOI:10.1021/ja01653a006

upstream raw materials:

nitrogen(II) oxide

ammonia

phosphorus trichloride

nitrogen

Downstream raw materials:

phosphan

PNO₂H₂

nitrogen

ammonium dihydrogenphosphite

Refernces

• 1、 McCallum, K. J.,Leifer, E.. "". . p. 505. Retrieved 1940.
• 2、 Zeng, Xiaoqing,Beckers, Helmut,Willner, Helge,Francisco, Joseph S.. "Experimental observation of the 16-electron molecules SPN, SNP, and cyclic PSN". . p. 3334 - 3339. Retrieved 2012/06/15.
• 3、 Ahlrichs, Reinhart,Baer, Michael,Plitt, Harald S.,Schnoeckel, Hansgeorg. "The stability of PN and (PN)3. Ab initio calculations and matrix infrared investigations". . p. 179 - 184. Retrieved 2008/10/08.