Benzaldehyde, 3-(1,1-dimethylethyl)-2-hydroxy-5-methyl-, oxime

Base Information

Chemical Name:Benzaldehyde, 3-(1,1-dimethylethyl)-2-hydroxy-5-methyl-, oxime
CAS No.:72357-42-7
Molecular Formula:C12H17NO2
Molecular Weight:207.272
Hs Code.:

Synonyms:

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Chemical Property of Benzaldehyde, 3-(1,1-dimethylethyl)-2-hydroxy-5-methyl-, oxime

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Technology Process of Benzaldehyde, 3-(1,1-dimethylethyl)-2-hydroxy-5-methyl-, oxime

There total 2 articles about Benzaldehyde, 3-(1,1-dimethylethyl)-2-hydroxy-5-methyl-, oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 41715-31-5
3-tert-butyl-5-methylsalicylaldehyde

: 72357-42-7
3-tert-butyl-5-methylsalicylaldoxime

Guidance literature:: With hydroxylamine hydrochloride; In dimethyl sulfoxide; at 20 ℃; for 0.333333h;
DOI:10.1016/j.tetlet.2011.07.070

Reference yield:

: 2409-55-4
2-tert-Butyl-4-methylphenol

: 72357-42-7
3-tert-butyl-5-methylsalicylaldoxime

Guidance literature:: Multi-step reaction with 2 steps

1.1: tin(IV) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 0.33 h / 20 °C / Inert atmosphere

1.2: 8 h / 100 °C / Inert atmosphere

2.1: hydroxylamine hydrochloride / dimethyl sulfoxide / 0.33 h / 20 °C

With hydroxylamine hydrochloride; tin(IV) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dimethyl sulfoxide; toluene; 1.1: Casiraghi reaction / 1.2: Casiraghi reaction;
DOI:10.1016/j.tetlet.2011.07.070

Reference yield: 42.0%

: 67-56-1
methanol

: manganese(II) perchlorate hexahydrate

: 72357-42-7
3-tert-butyl-5-methylsalicylaldoxime

: 51437-68-4,100462-49-5,104959-61-7
sodium formate dihydrate

: Mn₃O(3-tert-butyl-5-methylsalicylaldoxime)3(HCOO)(CH₃OH)4*2CH₃OH

Guidance literature:: With NaOCH₃; In methanol; to Mn-compd. in CH3OH added Na-compd. and aldoxime-compd. and then NaOCH3 added, stirred for 1 h; slowly evaporated for one week, filtered, washed with cold MeOH and Et2O, elem. anal.;
DOI:10.1002/ejic.200901244