Stannane, tributyl(5-phenyl-2-pentenyl)-

Base Information

Chemical Name:Stannane, tributyl(5-phenyl-2-pentenyl)-
CAS No.:74940-41-3
Molecular Formula:C₂₃H₄₀Sn
Molecular Weight:435.281
Hs Code.:

Synonyms:

Suppliers and Price of Stannane, tributyl(5-phenyl-2-pentenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Stannane, tributyl(5-phenyl-2-pentenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Stannane, tributyl(5-phenyl-2-pentenyl)-

There total 1 articles about Stannane, tributyl(5-phenyl-2-pentenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 4226-01-1
tri-n-butyltin lithium

: 117785-41-8
C₆H₅(CH₂)2CHCHCH₂SC₆H₅

: 74940-41-3
1-(tributylstannyl)-5-phenyl-2-pentene

Guidance literature:: With copper(I) bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; addn. of a soln. of tributylstannyllithium in THF to a mixt. of the thiobutene and CuBr in THF/HMPT under Ar with stirring (0°C or room temp., 2-6 h); quenching with phosphate buffer soln. (pH 7), extn. with CH2Cl2, drying over Na2SO4, concg. under reduced pressure, chromy. on silica gel (hexane), IR, NMR, 31 to 77 % yield at various conditions;
DOI:10.1246/cl.1987.1967

Reference yield: 58.0%

: 6651-36-1
1-(Trimethylsilyloxy)cyclohexene

: 74940-41-3
1-(tributylstannyl)-5-phenyl-2-pentene

: 2-(1-Phenethyl-allyl)-cyclohexanone

: 125163-43-1
2-(5-phenyl-2-pentenyl)cyclohexanone

Guidance literature:: With copper(II) trifluoroacetate; In benzene; To a benzene suspn. of copper(II) trifluoroacetate and molecular sieves 3A is added a benzene soln. of allylstannane and silylether, stirring for 1 d, room temp.; Addn. of H2O, extn. (CH2Cl2), extract is washed with aq. KF soln., dried over Na2SO4, and condensed under reduced pressure, residue is chromd. on silica gel (hexane/AcOEt), overall yield 58 %, NMR (ratio α:γ-coupling product >95:<5).;

Reference yield:

: 64-17-5
ethanol

: 74940-41-3
1-(tributylstannyl)-5-phenyl-2-pentene

: 53963-40-9
(3-Ethoxy-pent-4-enyl)-benzene

: 122894-79-5
((E)-5-Ethoxy-pent-3-enyl)-benzene

Guidance literature:: With copper(ll) bromide; In tetrahydrofuran; at 0 - 25 ℃; Yield given. Yields of byproduct given;
DOI:10.1246/cl.1988.985