(6R)-6,10-Dimethylundeca-3,9-dien-2-one

Base Information

Chemical Name:(6R)-6,10-Dimethylundeca-3,9-dien-2-one
CAS No.:76832-12-7
Molecular Formula:C13H22O
Molecular Weight:194.317
Hs Code.:
DSSTox Substance ID:DTXSID20710497

Synonyms:76832-12-7;(6R)-6,10-Dimethylundeca-3,9-dien-2-one;DTXSID20710497

Suppliers and Price of (6R)-6,10-Dimethylundeca-3,9-dien-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of (6R)-6,10-Dimethylundeca-3,9-dien-2-one

Chemical Property:

PSA：17.07000
LogP:3.90420
XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:194.167065321
Heavy Atom Count:14
Complexity:219

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CCC=C(C)C)CC=CC(=O)C
Isomeric SMILES:C[C@H](CCC=C(C)C)CC=CC(=O)C

Technology Process of (6R)-6,10-Dimethylundeca-3,9-dien-2-one

There total 1 articles about (6R)-6,10-Dimethylundeca-3,9-dien-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 2385-77-5
(R)-Citronellal

: 67-64-1
acetone

: 76832-12-7
(6R)-(E)-6,10-dimethyl-3,9-undecadien-2-one

Guidance literature:: With [bmim]PF₆; N-methyl-3-aminopropylated amorphous silica; at 50 ℃; for 21h;

Reference yield:

: 76832-12-7
(6R)-(E)-6,10-dimethyl-3,9-undecadien-2-one

: 59-02-9,18920-62-2
Tocopherol

Guidance literature:: Multi-step reaction with 9 steps

1: (iPrO)3Al / propan-2-ol; acetone / 5.5 h / Heating

2: DMAP, pyridine / 3 h / Ambient temperature

3: 46 percent / aq. NaOH, monobasic potassium phosphate, Triton X-100 / lipase ex Pseudomonas fluorescens

4: 1.) n-BuLi / 1.) THF, hexane, 30 min, 2.) THF, hexane, RT, overnight

5: 96 percent / NaH, Pd(PPh₃)4 / tetrahydrofuran / -78 - 20 °C

6: 99.9 percent / NaBH₄ / methanol / 52 h

7: 100 percent / aq. NaOH / methanol; tetrahydrofuran / Heating

8: 45.9 percent / Me₂NCH(OBu-t)2 / toluene / 60 °C

9: 1.) H₂, 2.) H₂ / 1.) 5percent Pt/C, 2.) 10percent Pd/C / 1.) EtOAc, 25 deg C, 500 psi, 4 h, 2.) EtOH, THF, 60 psi, 4 h

With pyridine; dmap; sodium hydroxide; sodium tetrahydroborate; potassium dihydrogenphosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; hydrogen; aluminum isopropoxide; sodium hydride; Triton X-100; N,N-dimethylformamide di-tert-butyl acetal; palladium on activated charcoal; platinum on activated charcoal; In tetrahydrofuran; methanol; isopropyl alcohol; acetone; toluene;

Reference yield:

: 76832-12-7
(6R)-(E)-6,10-dimethyl-3,9-undecadien-2-one

: 59965-06-9
Vitamin E benzyl ether

Guidance literature:: Multi-step reaction with 10 steps

1: (iPrO)3Al / propan-2-ol; acetone / 5.5 h / Heating

2: DMAP, pyridine / 3 h / Ambient temperature

3: 46 percent / aq. NaOH, monobasic potassium phosphate, Triton X-100 / lipase ex Pseudomonas fluorescens

4: 1.) n-BuLi / 1.) THF, hexane, 30 min, 2.) THF, hexane, RT, overnight

5: 97.7 percent / NaH, Pd(PPh₃)4 / tetrahydrofuran / -78 - 20 °C

6: DIBAL / toluene / 1 h / 0 °C

7: pyridine / 20 h / Ambient temperature

8: DBN / diethyl ether / Ambient temperature

9: Na₂S₂O₄, NaHCO₃, H₂O, Aliquot 336 / cyclohexane / Heating

10: H₂ / 10percent Pt/C / ethyl acetate / 8 °C / 25857.4 Torr

With pyridine; dmap; sodium hydroxide; potassium dihydrogenphosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; sodium dithionite; 2,6-dichloro-benzonitrile; water; hydrogen; aluminum isopropoxide; Aliquat 336; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Triton X-100; platinum on activated charcoal; In tetrahydrofuran; diethyl ether; cyclohexane; ethyl acetate; isopropyl alcohol; acetone; toluene;