Diallylformamide

Base Information

• Chemical Name: Diallylformamide
• CAS No.: 18889-09-3
• Molecular Formula: C7H11 N O
• Molecular Weight: 125.17
• Hs Code.: 2924199090
• Mol file: 18889-09-3.mol

Synonyms:Formamide,N,N-di-2-propenyl- (9CI); Formamide, N,N-diallyl- (6CI,7CI,8CI);Diallylformamide; N,N-Di-2-propenylformamide; N,N-Diallylformamide;N-Formyldiallylamine; NSC 59281

Chemical Property of Diallylformamide

Chemical Property:

• Vapor Pressure: 0.101mmHg at 25°C
• Boiling Point: 222.5°Cat760mmHg
• PKA: -0.62±0.70(Predicted)
• Flash Point: 83.3°C
• PSA: 20.31000
• Density: 0.901g/cm³
• LogP: 1.45270

Purity/Quality:

99%min ^*data from raw suppliers

N,N-Diallylformamide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of Diallylformamide

There total 6 articles about Diallylformamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

carbon dioxide (124-38-9,18923-20-1) + diallylamine (124-02-7) → N,N-diallylcarboxamide (18889-09-3)

Guidance literature:

With phenylsilane; In neat (no solvent); at 35 ℃; for 14h; under 7500.75 Torr; Autoclave;

DOI:10.1039/c8ta00823j

Reference yield: 97.0%

diallylamine (124-02-7) + formic acid ethyl ester (109-94-4) → N,N-diallylcarboxamide (18889-09-3)

Guidance literature:

for 22h; Heating;

DOI:10.1021/ja00238a018

Reference yield: 89.0%

Triallylamine (102-70-5) → N,N-diallylcarboxamide (18889-09-3)

Guidance literature:

With manganese(IV) oxide; oxygen; In chlorobenzene; at 100 ℃; for 4h; under 4500.45 Torr; Autoclave; Green chemistry;

upstream raw materials:

diallylamine

formic acid ethyl ester

carbon dioxide

(formyloxy)(acetoxy)phenylmethane

Downstream raw materials:

N,N-diallylbenzamide

N-Formyl-2,6-dimethyl-thiomorpholine

Refernces

• 1、 Huang, Hsin-Yi,Liang, Chien-Fu,Lin, Xiu-Yi,Yen, Shih-Yao. "Facile access to: N-formyl imide as an N-formylating agent for the direct synthesis of N-formamides, benzimidazoles and quinazolinones". supporting information. p. 5726 - 5733. Retrieved 2020/08/21.
• 2、 Luo, Rongchang,Lin, Xiaowei,Chen, Yaju,Zhang, Wuying,Zhou, Xiantai,Ji, Hongbing. "Cooperative Catalytic Activation of Si?H Bonds: CO2-Based Synthesis of Formamides from Amines and Hydrosilanes under Mild Conditions". . p. 1224 - 1232. Retrieved 2017/03/29.