N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide

Base Information

• Chemical Name: N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide
• CAS No.: 832114-07-5
• Molecular Formula: C15H22BNO3
• Molecular Weight: 275.156
• Hs Code.: 2934999090
• European Community (EC) Number: 675-077-2
• DSSTox Substance ID: DTXSID40374434
• Nikkaji Number: J3.440.692H
• Wikidata: Q82163028
• Mol file: 832114-07-5.mol

Synonyms:832114-07-5;N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide;3-(N,N-Dimethylaminocarbonyl)phenylboronic acid pinacol ester;3-(Dimethylcarbamoyl)benzeneboronic acid pinacol ester;3-(n,n-dimethylaminocarbonyl)phenylboronic acid, pinacol ester;SCHEMBL1290866;DTXSID40374434;N,N-dimethyl-3-(tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide;MFCD05863907;AKOS015960128;AB22698;FS-5380;CS-0175654;FT-0761461;E84166;EN300-7363686;A864300;Z1741964493;3-(N,N-Dimethylaminocarbonyl)phenylboronic acid, pinacol ester, AldrichCPR;n,n-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzamide;N,N-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide, AldrichCPR

Chemical Property of N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide

Chemical Property:

• Vapor Pressure: 3.93E-07mmHg at 25°C
• PSA: 38.77000
• LogP: 1.68760
• Storage Temp.: Keep Cold
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 275.1692737
• Heavy Atom Count: 20
• Complexity: 365

Purity/Quality:

97% ^*data from raw suppliers

3-(N,N-Dimethylaminocarbonyl)phenylboronic acid, pinacol ester ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 43
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B1(OC(C(O1)(C)C)(C)C)C2=CC(=CC=C2)C(=O)N(C)C
• Uses: 3-(N,N-Dimethylaminocarbonyl)phenylboronic acid pinacol ester

Technology Process of N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide

There total 10 articles about N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

bis(pinacol)diborane (73183-34-3) + N,N-dimethylbenzamide (611-74-5) → N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide (832114-07-5)

Guidance literature:

With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; C₁₉H₁₃N₃O; potassium tert-butylate; In tetrahydrofuran; at 80 ℃; for 12h; Reagent/catalyst; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1002/anie.201809929

Reference yield: 25.0%

bis(pinacol)diborane (73183-34-3) + N,N-dimethylbenzamide (611-74-5) → N,N-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide (956229-73-5) + N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide (832114-07-5) + N,N-dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide (400727-57-3)

Guidance literature:

With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; N-(2,3-dimethyl-1H-indol-7-yl)-[2,2'-bipyridine]-5-carboxamide; In tetrahydrofuran; at 50 ℃; for 24h; regioselective reaction; Inert atmosphere; Glovebox;

DOI:10.1002/anie.201907366

Reference yield:

3-bromo-N,N-dimethylbenzamide (24167-51-9) + bis(pinacol)diborane (73183-34-3) → N,N-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide (832114-07-5)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; for 2h; Reflux; Inert atmosphere;

DOI:10.1016/j.ejmech.2015.04.037

upstream raw materials:

N,N-dimethylbenzamide

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

bis(pinacol)diborane

3-bromo-N,N-dimethylbenzamide

Downstream raw materials:

cyclohexylcarbamic acid 6-benzyloxy-3′-dimethylcarbamoylbiphenyl-3-yl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 832114-07-5 3-(N,N-DIMETHYLAMINOCARBONYL)PHENYLBORONIC ACID, PINACOL ESTER

Send

Send

Metric Ton KG G Pound L ML

Send

Send