Rhamnulose

Base Information

• Chemical Name: Rhamnulose
• CAS No.: 14807-05-7
• Molecular Formula: C6H12 O5
• Molecular Weight: 164.158
• Mol file: 14807-05-7.mol

Synonyms:Fructose,6-deoxy-, L- (8CI); L-Rhamnulose

Chemical Property of Rhamnulose

Chemical Property:

• Boiling Point: 323.9°Cat760mmHg
• Flash Point: 149.7°C
• PSA: 97.99000
• Density: 1.556g/cm³
• LogP: -2.34960

Purity/Quality:

95% ^*data from raw suppliers

L-Rhamnulose ≥80% (HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Rhamnulose

There total 19 articles about Rhamnulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-deoxy-L-altritol (73804-38-3) → L-fuculose (3616-21-5,4429-06-5,6748-00-1,14807-05-7,18545-94-3,18546-17-3,27180-09-2,77449-10-6,99945-92-3,138382-50-0,13074-08-3)

Guidance literature:

With Enterobacter aerogenes IK₇; In water; at 37 ℃; pH=9; aq. Tris-HCl buffer; Aerobic conditions; Microbiological reaction;

DOI:10.1016/j.tetlet.2009.12.024

Reference yield: 100.0%

dihydroxyacetone (96-26-4,26776-70-5) + 2(S)-hydroxypropanal (3913-64-2) → 6-deoxy-L-arabino-2-hexulose (14807-05-7)

Guidance literature:

With L-rhamnulose-1-phosphate aldolase; at 25 ℃; for 24h; pH=7; stereoselective reaction; aq. sodium borate buffer; Enzymatic reaction;

DOI:10.1002/adsc.201000719

Reference yield: 84.0%

L-Fuculose-1-phosphate (92418-41-2) → L-fuculose (3616-21-5,4429-06-5,6748-00-1,14807-05-7,18545-94-3,18546-17-3,27180-09-2,77449-10-6,99945-92-3,138382-50-0,13074-08-3)

Guidance literature:

With hydrogenchloride; acid?phosphatase from Escherichia coli; magnesium(II); zinc(II) cation; In water; at 37 ℃; pH=5.5;

DOI:10.1016/j.bmcl.2015.12.051

upstream raw materials:

pyridine

L-Fucose

L-Fuculose-1-phosphate

1-deoxy-L-altritol

Downstream raw materials:

6-Deoxy-L-talose

6-deoxy-L-glucose

C₁₀H₁₃NO₃

6-deoxy-L-fructose 2-nitrophenylhydrazone