6-Deoxy-L-glucose

Base Information

• Chemical Name: 6-Deoxy-L-glucose
• CAS No.: 35867-45-9
• Molecular Formula: C6H12 O5
• Molecular Weight: 164.158
• Hs Code.: 2912491000
• UNII: TB3C1ME2M8
• DSSTox Substance ID: DTXSID70574147
• Nikkaji Number: J89.059F
• Mol file: 35867-45-9.mol

Synonyms:6-Deoxy-L-glucose;L-6-Deoxyglucose; L-Chinovose; L-Isorhamnose; L-Quinovose

Chemical Property of 6-Deoxy-L-glucose

Chemical Property:

• PSA: 90.15000
• LogP: -2.19380
• XLogP3: -2.4
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 164.06847348
• Heavy Atom Count: 11
• Complexity: 126

Purity/Quality:

98% ^*data from raw suppliers

6-Deoxy L-glucose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C(C(C(C=O)O)O)O)O
• Isomeric SMILES: C[C@@H]([C@@H]([C@H]([C@@H](C=O)O)O)O)O

Technology Process of 6-Deoxy-L-glucose

There total 100 articles about 6-Deoxy-L-glucose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tigogenin-3-O-α-L-rhamnopyranosyl-(1->4)-β-D-glucopyranosyl-(1->3)-β-D-xylopyranosyl-(1->4)-β-D-glucopyranosyl-(1->4)-β-D-xylopyranoside → tigogenin (77-60-1) + D-xylose (58-86-6) + 6-deoxy-L-glucose (35867-45-9,478518-52-4) + D-glucose (50-99-7)

Guidance literature:

With hydrogenchloride; In water; at 100 ℃; for 2h;

DOI:10.1080/14786410902986597

Reference yield:

polysaccharide from Abelmoschus esculentus (L.) Moench → D-Fructose (57-48-7,18875-34-8) + D-xylose (58-86-6) + D-Mannose (3458-28-4) + D-Arabinose (10323-20-3) + D-rhamnose (634-74-2,2438-80-4,3615-37-0,3615-41-6,3713-31-3,4348-84-9,5158-61-2,5624-55-5,5652-45-9,7420-19-1,7658-08-4,7658-09-5,7658-10-8,7724-73-4,10485-94-6,18546-02-6,18546-05-9,19479-17-5,32738-74-2,35867-45-9,39665-53-7,64364-07-4,75247-25-5,78684-66-9,84985-25-1,478518-52-4) + D-glucose (50-99-7) + D-Galactose (59-23-4)

Guidance literature:

With water; trifluoroacetic acid; at 120 ℃; for 2h;

DOI:10.1016/j.ijbiomac.2018.03.145

Reference yield:

polysaccharide from Artemisia argyi, MW 5169 Da → D-xylose (58-86-6) + D-Mannose (3458-28-4) + D-Arabinose (10323-20-3) + D-ribose (50-69-1) + D-rhamnose (634-74-2,2438-80-4,3615-37-0,3615-41-6,3713-31-3,4348-84-9,5158-61-2,5624-55-5,5652-45-9,7420-19-1,7658-08-4,7658-09-5,7658-10-8,7724-73-4,10485-94-6,18546-02-6,18546-05-9,19479-17-5,32738-74-2,35867-45-9,39665-53-7,64364-07-4,75247-25-5,78684-66-9,84985-25-1,478518-52-4) + D-glucose (50-99-7) + D-Galactose (59-23-4) + 2-acetamido-2-deoxy-D-glucose (7512-17-6,282727-46-2,478518-83-1,127959-06-2,78393-48-3)

Guidance literature:

With trifluoroacetic acid; In water; at 100 ℃; for 8h; Sealed tube;

DOI:10.1016/j.carbpol.2013.07.018

upstream raw materials:

(2S,3S,4S,5S,6R)-2-methoxy-6-methyltetrahydro-2H-pyran-3,4,5-triol

C₄₇H₆₁NO₂₇

pseudo-ginsenoside-RS₁

sulfuric acid

Downstream raw materials:

D,L-rhamnose

trifluoroacetylated 6-deoxymannose anti-O-benzyloxime

trifluoroacetylated 6-deoxymannose syn-O-benzyloxime

5-Methylfurfural