DNP-sarcosine

Base Information

• Chemical Name: DNP-sarcosine
• CAS No.: 3129-54-2
• Molecular Formula: C9H9N3O6
• Molecular Weight: 255.18
• Hs Code.: 2922499990
• NSC Number: 96394
• Mol file: 3129-54-2.mol

Synonyms:DNP-sarcosine;3129-54-2;N-2,4-DNP-SARCOSINE;N-(2,4-Dinitrophenyl)-sarcosine;n-(2,4-dinitrophenyl)-n-methylglycine;2-(N-methyl-2,4-dinitroanilino)acetic acid;DNP-Sarkosin;NSC96394;N-(2,4-Dinitrophenyl)-DL-sarcosine;2-((2,4-dinitrophenyl)(methyl)amino)acetic acid;SCHEMBL3491006;MFCD00057600;NSC-96394;AKOS010135239;[2,4-dinitro(methyl)anilino]acetic acid;AS-56438;SY272893;CS-0327926;FT-0759289;AR-299/42656434

Chemical Property of DNP-sarcosine

Chemical Property:

• Vapor Pressure: 4.2E-10mmHg at 25°C
• Refractive Index: 1.659
• Boiling Point: 482 °C at 760 mmHg
• Flash Point: 245.3 °C
• PSA: 132.18000
• Density: 1.572 g/cm³
• LogP: 2.07020
• Storage Temp.: −20°C
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 255.04913502
• Heavy Atom Count: 18
• Complexity: 349

Purity/Quality:

99% ^*data from raw suppliers

N-(2,4-DINITROPHENYL)-SARCOSINE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(CC(=O)O)C1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of DNP-sarcosine

There total 2 articles about DNP-sarcosine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

sarcosine (107-97-1,25951-24-0) + 2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) → N-(2,4-dinitrophenyl)sarcosine (3129-54-2)

Guidance literature:

With sodium hydrogencarbonate; In ethanol; water;

DOI:10.1002/ejoc.200300028

Reference yield: 96.0%

sarcosine (107-97-1,25951-24-0) + 1-chloro-2,4-dinitro-benzene (97-00-7) → N-(2,4-dinitrophenyl)sarcosine (3129-54-2)

Guidance literature:

With sodium hydrogencarbonate; In ethanol; for 6h; Heating;

Reference yield: 81.0%

ethanol (64-17-5) + N-(2,4-dinitrophenyl)sarcosine (3129-54-2) → N-methyl-N-(2,4-dinitrophenyl)glycine ethyl ester (116059-06-4)

Guidance literature:

With hydrogenchloride; In ethanol; for 5h; Heating;

upstream raw materials:

sarcosine

2,4-Dinitrofluorobenzene

1-chloro-2,4-dinitro-benzene

Downstream raw materials:

N-methyl-N-(2,4-dinitrophenyl)glycine ethyl ester

2-amino-2'-methylamino-5,5'-dinitro-ONN-azoxybenzene

2,2'-bis(methylamino)-5,5'-dinitroazoxybenzene

2-acetamido-2'-(N-methylacetamido)-5,5'-dinitro-ONN-azoxybenzene

Refernces

• 1、 McFarlane, Michael D.,Smith, David M.,Ferguson, George,Kaitner, Branko. "o-Nitroaniline Derivatives. Part 12. The Reaction of N-(2,4-Dinitrophenyl)-sarcosine Ethyl Ester with Bases: Some Novel Redox Processes Revealed by X-Ray Crystallography". . p. 893 - 902. Retrieved 2007/10/02.