Benzeneethanamine, b-phenyl-N-(phenylmethyl)-b-2-propenyl-

Base Information

• Chemical Name: Benzeneethanamine, b-phenyl-N-(phenylmethyl)-b-2-propenyl-
• CAS No.: 846576-78-1
• Molecular Formula: C24H25N
• Molecular Weight: 327.469

Synonyms:

Chemical Property of Benzeneethanamine, b-phenyl-N-(phenylmethyl)-b-2-propenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzeneethanamine, b-phenyl-N-(phenylmethyl)-b-2-propenyl-

There total 5 articles about Benzeneethanamine, b-phenyl-N-(phenylmethyl)-b-2-propenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

2,2-diphenyl-4-pentenylamine (53001-06-2) + benzaldehyde (100-52-7) → benzyl(2,2-diphenyl-4-pentenyl)amine (846576-78-1)

Guidance literature:

2,2-diphenyl-4-pentenylamine; benzaldehyde; In methanol; at 20 ℃; for 5h;

With sodium tetrahydroborate; In methanol;

DOI:10.1016/j.tetlet.2012.06.033

Reference yield: 86.0%

C24H23N (194989-15-6) → benzyl(2,2-diphenyl-4-pentenyl)amine (846576-78-1)

Guidance literature:

With methanol; sodium tetrahydroborate;

DOI:10.1002/adsc.201200352

Reference yield:

Diphenylacetonitrile (86-29-3) → benzyl(2,2-diphenyl-4-pentenyl)amine (846576-78-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: NaH / dimethylformamide / 1 h / 20 °C

1.2: dimethylformamide / 20 °C

2.1: LiAlH₄ / diethyl ether / 20 °C

3.1: methanol / 3.5 h / 20 °C

3.2: 3.48 g / NaBH₄ / methanol

With lithium aluminium tetrahydride; sodium hydride; In methanol; diethyl ether; N,N-dimethyl-formamide;

DOI:10.1021/ja043278q

upstream raw materials:

2,2-diphenyl-4-pentenylamine

benzaldehyde

Diphenylacetonitrile

2,2-diphenyl-pent-4-enenitrile

Downstream raw materials:

trans-[(CH₂CHCH₂C(C₆H₅)2CH₂NHCH₂C₆H₅)PtCl₂(PPh₃)]

(S)-1-benzyl-2-methyl-4,4-diphenylpyrrolidine

N-benzyl-N-(2,2-diphenylpent-4-enyl)-6-methyltridec-7-yn-6-amine

1-benzyl-2-(chloromethyl)-4,4-diphenylpyrrolidine

Refernces

Chiral NHC-Iridium Complexes and Their Performance in Enantioselective Intramolecular Hydroamination and Ring-Opening Amination Reactions

10.1021/acs.organomet.9b00770

The research focuses on the synthesis and characterization of chiral N-heterocyclic carbene (NHC) iridium complexes, which are investigated for their performance in enantioselective intramolecular hydroamination and ring-opening amination reactions. The study involves the preparation of a series of chiral NHC-iridium complexes with different diene ligands, such as TFB, TCB, BB, and COD. These complexes were synthesized and fully characterized using techniques like X-ray crystallography and NMR spectroscopy. The reactivity and enantioselectivity of these complexes were evaluated in the enantioselective intramolecular hydroamination of N-benzyl-2,2-diphenylpent-4-en-1-amine and the enantioselective ring-opening amination of oxabicycles. The experiments utilized various reactants, including different NHC salts and iridium precursors, and analyses were conducted using 1H and 13C NMR spectroscopy, elemental analysis, and HPLC to determine the yields and enantioselectivities of the reactions. The research also explored the impact of electronic and steric variations on the catalyst platform and identified a highly enantioselective catalyst system for the ring-opening amination of oxabicycles.

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