Chlorotris(4-methoxyphenyl)stannane

Base Information

• Chemical Name: Chlorotris(4-methoxyphenyl)stannane
• CAS No.: 84761-55-7
• Molecular Formula: C₂₁H₂₁ClO₃Sn
• Molecular Weight: 475.559
• DSSTox Substance ID: DTXSID20514235
• Wikidata: Q82374436
• Mol file: 84761-55-7.mol

Synonyms:Chlorotris(4-methoxyphenyl)stannane;84761-55-7;DTXSID20514235

Chemical Property of Chlorotris(4-methoxyphenyl)stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 476.020125
• Heavy Atom Count: 26
• Complexity: 352

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)[Sn](C2=CC=C(C=C2)OC)(C3=CC=C(C=C3)OC)Cl

Technology Process of Chlorotris(4-methoxyphenyl)stannane

There total 1 articles about Chlorotris(4-methoxyphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrakis(p-methoxyphenyl)stannane (38178-34-6) + tin(IV) chloride (7646-78-8) → mono-chloro-tri-(4-methoxyphenyl)stannane (84761-55-7)

Guidance literature:

In not given; Kocheshkov redistribution reaction (K. A. Kocheshkov, M. M. Nadi and A. P. Aleksandrov Chem. Ber. 67 (1934) 1348; recrystn. from hexane, elem. anal.;

DOI:10.1016/S0020-1693(00)80893-2

Reference yield: 75.0%

dimanganese decacarbonyl (10170-69-1) + mono-chloro-tri-(4-methoxyphenyl)stannane (84761-55-7) + sodium (7440-23-5) → Mn(CO)5Sn(C6H4OCH3)3 (206194-55-0)

Guidance literature:

With Hg; In tetrahydrofuran; Mn2(CO)10 in THF was stirred with sodium amalgam for 30 min at room temp., sepd., Sn-salt was added, stirred for 40 min, poured on ice; extd. with boiling hexane, evapd., cooled, recystd.;

DOI:10.1016/S0020-1693(01)00792-7

Reference yield: 51.1%

hydrogenchloride (7647-01-0,15364-23-5) + mono-chloro-tri-(4-methoxyphenyl)stannane (84761-55-7) → dichloro[bis(p-methoxyphenyl)]stannane (56541-97-0)

Guidance literature:

In diethyl ether; benzene; at 0 - 20 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c8dt03043j

upstream raw materials:

tetrakis(p-methoxyphenyl)stannane

tin(IV) chloride

Downstream raw materials:

(CH₃OC₆H₄)3SnCH₂C₆H₄F

Mn(CO)5Sn(C₆H₄OCH₃)3

dichloro[bis(p-methoxyphenyl)]stannane