(4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)

Base Information

Chemical Name:(4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)
CAS No.:18649-43-9
Molecular Formula:C13H19O7Pb
Molecular Weight:491.466
Hs Code.:
DSSTox Substance ID:DTXSID40586732
NSC Number:314093
Wikidata:Q82478915

Synonyms:18649-43-9;Tris(acetyloxy)(4-methoxyphenyl)plumbane;4-methoxyphenyllead triacetate;SCHEMBL3521493;DTXSID40586732;NSC314093;NSC-314093

Suppliers and Price of (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:8
Exact Mass:492.06625
Heavy Atom Count:21
Complexity:361

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)O[Pb](C1=CC=C(C=C1)OC)(OC(=O)C)OC(=O)C

Technology Process of (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3)

There total 3 articles about (4-methoxyphenyl)-lambda~2~-plumbanyl - acetic acid (1:3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: lead(IV) tetraacetate

: 13257-51-7
mercury(II) trifluoroacetate

: 70744-47-7
(p-methoxyphenyl)tri-n-butylstannane

: 18649-43-9
4-methoxyphenyllead triacetate

Guidance literature:: In chloroform; addn. of Sn-compd. and Hg(OOCCF3) to a soln. of Pb(OAc)4 in CHCl3, stirring at 40°C overnight; filtration (Kieselgur), evapn. of filtrate (vac., 40°C), dissoln. of oily residue in petroleum ether (40-60°C), crystn. on storing in refrigerator, recrystn. from CHCl3/petroleum ether; elem. anal.;
DOI:10.1016/0022-328X(92)83382-R

Reference yield: 60.0%

: 546-67-8
lead(IV) tetraacetate

: 100-66-3
methoxybenzene

: 18649-43-9
4-methoxyphenyllead(IV) triacetate

Guidance literature:: With dichloro-acetic acid; In chloroform; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1039/c2cc36452b

Reference yield: 33.0%

: 5720-07-0
4-methoxyphenylboronic acid

: 546-67-8
lead(IV) tetraacetate

: 18649-43-9
4-methoxyphenyllead(IV) triacetate

Guidance literature:: mercury(II) diacetate; In chloroform; addn. of B-compd. to stirred mixt. of Pb-compd. and Hg-compd. in CHCl3 over 15 min (40°C), stirring (40°C, 1 h and room temp. overnight); filtration (Celite), concn. (40°C), addn. of petroleum ether, standing (0°C, overnight), stirring in mixt. of acetic acid and CHCl3, washing (H2O), drying (Na2SO4), concn., addn. of petroleum ether, crystn. (0°C);