Methylenediformamide

Base Information

• Chemical Name: Methylenediformamide
• CAS No.: 6921-98-8
• Molecular Formula: C3H6 N2 O2
• Molecular Weight: 102.093
• Hs Code.: 2924199090
• European Community (EC) Number: 230-041-1
• NSC Number: 21313
• UNII: 3SB88US9EV
• DSSTox Substance ID: DTXSID9064504
• Nikkaji Number: J256.596J
• Wikidata: Q81991612
• Mol file: 6921-98-8.mol

Synonyms:Methylenediformamide;6921-98-8;N,N'-Methylenebisformamide;n,n'-methylenediformamide;N-(formamidomethyl)formamide;Methylenebisformamide;Formamide, N,N'-methylenebis-;N,N-Methylenebisformamide;3SB88US9EV;N,N'-Methylenebis(formamide);AI3-60011;EINECS 230-041-1;NSC 21313;NSC-21313;N,N'-Methylenebis[formamide];NSC21313;methylene-bis-formamide;UNII-3SB88US9EV;Formamide,N'-methylenebis-;SCHEMBL633964;DTXSID9064504;C H2 (N H C H O)2;MFCD00021038;AKOS006220753;BS-49292;CS-0197372;FT-0629593;M0978;E78232;A853407

Chemical Property of Methylenediformamide

Chemical Property:

• Vapor Pressure: 1.15E-10mmHg at 25°C
• Melting Point: 141-143°C
• Boiling Point: 513.7°C at 760 mmHg
• Flash Point: 275.1°C
• PSA: 58.20000
• Density: 1.13g/cm³
• LogP: 0.48950
• XLogP3: -1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 102.042927438
• Heavy Atom Count: 7
• Complexity: 56

Purity/Quality:

97% ^*data from raw suppliers

N,N'-Methylenediformamide 97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(NC=O)NC=O
• Uses: N,N''-Methylenediformamideis a useful reagent in the synthesis of Hexamethylene Triperoxide Diamine (CAS:283-66-9)

Technology Process of Methylenediformamide

There total 5 articles about Methylenediformamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexamethylenetetramine (100-97-0) + formamide (77287-34-4,77287-35-5,60100-09-6) → Bis(formamido)methane (6921-98-8)

Guidance literature:

at 140 ℃;

DOI:10.1021/ja01614a064

Reference yield:

chloromethyl propyl ether (3587-57-3) + formamide (77287-34-4,77287-35-5,60100-09-6) → Bis(formamido)methane (6921-98-8)

Guidance literature:

at 120 ℃;

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + formamide (77287-34-4,77287-35-5,60100-09-6) → Bis(formamido)methane (6921-98-8)

Guidance literature:

DOI:10.1002/ardp.19642971003

upstream raw materials:

hexamethylenetetramine

formamide

chloromethyl propyl ether

formaldehyd

Downstream raw materials:

N,N'-methylenebisbenzamide

4,5-dimethyl-1H-imidazole hydrochloride

diaminomethane