Tungsten,pentacarbonyl(triphenylphosphine)-, (OC-6-22)-

Base Information

Chemical Name:Tungsten,pentacarbonyl(triphenylphosphine)-, (OC-6-22)-
CAS No.:15444-65-2
Molecular Formula:C23H15 O5 P W
Molecular Weight:586.193
Hs Code.:

Synonyms:(Triphenylphosphine)tungstenpentacarbonyl (6CI); Tungsten, pentacarbonyl(triphenylphosphine)- (7CI,8CI);Pentacarbonyl(triphenylphosphine)tungsten

Suppliers and Price of Tungsten,pentacarbonyl(triphenylphosphine)-, (OC-6-22)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Tungsten,pentacarbonyl(triphenylphosphine)-, (OC-6-22)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:587.024469
Heavy Atom Count:30
Complexity:407

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.[W]

Technology Process of Tungsten,pentacarbonyl(triphenylphosphine)-, (OC-6-22)-

There total 50 articles about Tungsten,pentacarbonyl(triphenylphosphine)-, (OC-6-22)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 15096-68-1
pentacarbonyl(acetonitrile)tungsten

: 15444-65-2
triphenylphosphine tungsten pentacarbonyl

Guidance literature:: With tetraethylammonium perchlorate; triphenylphosphine; In acetonitrile; Electrochem. Process; under Ar, stirred MeCN soln. of W complex and excess PPh3 (contg. 0.1 MEt4NClO4 as supporting electrolite) oxidized at 22°C on Pt electrodes at 0.5 V (vs. satd. NaCl SCE) for 1500 s;
DOI:10.1021/ja00375a016

Reference yield: 96.0%

: pentacarbonyl(N-ethyl-N'-pentacarbonyltungsten-3-hydropyrimidine-1,2-propadienylidene)tungsten

: 603-35-0
triphenylphosphine

: 15444-65-2
triphenylphosphine tungsten pentacarbonyl

: pentacarbonyl(N-ethyl-3-hydropyrimidine-1,2-propadienylidene)tungsten

Guidance literature:: In dichloromethane; (N2); a soln. of W complex treated with ligand, stirred for 120 min at ambient temp.; evapd. (vac.), chromd. (silica, CH2Cl2);
DOI:10.1021/om0603969

Reference yield: 92.0%

: 14040-11-0
tungsten hexacarbonyl

: 15444-65-2
triphenylphosphine tungsten pentacarbonyl

Guidance literature:: With triphenylphosphine; tetrakis(triphenylphosphine)platinum; In benzene; byproducts: CO; under N2, refluxing soln. of metal carbonyl, org. compd. and Pt(PPh3)4 in benzene (molar ratio metal carbonyl/org. compd./Pt(PPh3)4 1:1:0.1, 4 d), cooling (room temp.); removal of solvent (vac.), dissoln. (CH2Cl2), chromy. (silica gel, CH2Cl2/hexane 1:1), recrystn. (CH2Cl2/hexane);