ethyl 6-chloro-3-Methylpicolinate

Base Information Edit

Chemical Name:ethyl 6-chloro-3-Methylpicolinate
CAS No.:850864-54-9
Molecular Formula:C9H10ClNO2
Molecular Weight:199.63400
Hs Code.:2933399090
Mol file:850864-54-9.mol

Synonyms:Ethyl 6-chloro-3-methylpicolinate;6-chloro-3-methyl-pyridine-2-carboxylic acid ethyl ester;

Suppliers and Price of ethyl 6-chloro-3-Methylpicolinate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethyl6-chloro-3-methylpicolinate 95+%
1g
$ 538.00

Chemenu
ethyl6-chloro-3-methylpicolinate 95%
1g
$ 632.00

American Custom Chemicals Corporation
ETHYL-6-CHLORO-3-METHYLPICOLINATE 95.00%
5MG
$ 498.97

Total 9 raw suppliers

Chemical Property of ethyl 6-chloro-3-Methylpicolinate Edit

Chemical Property:

Boiling Point:302.9±37.0 °C(Predicted)
PKA:-0.39±0.10(Predicted)
PSA：39.19000
Density:1?+-.0.06 g/cm3(Predicted)
LogP:2.22010
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

NLT 98% ^*data from raw suppliers

Ethyl6-chloro-3-methylpicolinate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of ethyl 6-chloro-3-Methylpicolinate

There total 3 articles about ethyl 6-chloro-3-Methylpicolinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 850864-53-8
ethyl 3-methyl-1-oxido-pyridin-1-ium-2-carboxylate

: 850864-54-9
ethyl 6-chloro-3-methyl-pyridine-2-carboxylate

Guidance literature:: With N,N-dimethyl-formamide; trichlorophosphate; In dichloromethane; at 0 - 20 ℃;

Reference yield: 70.0%

: 58997-10-7
ethyl 3-methylpyridine-2-carboxylate

: 850864-54-9
ethyl 6-chloro-3-methyl-pyridine-2-carboxylate

Guidance literature:: ethyl 3-methylpyridine-2-carboxylate; With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;

With trichlorophosphate; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1016/j.ejmech.2021.114036

Reference yield:

: 4021-07-2
3-methyl-pyridine-2-carboxylic acid

: 850864-54-9
ethyl 6-chloro-3-methyl-pyridine-2-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: thionyl chloride / 5 h / -20 °C / Reflux

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 16 h / 20 °C

3: trichlorophosphate / N,N-dimethyl-formamide / 1 h / 0 °C / Cooling with ice

With thionyl chloride; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In dichloromethane; N,N-dimethyl-formamide;