Technology Process of Gold, (3-methoxyphenyl)(triphenylphosphine)-
There total 2 articles about Gold, (3-methoxyphenyl)(triphenylphosphine)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
caesium carbonate;
In
isopropyl alcohol;
Cs2CO3 was added to a soln. of boronic acid in isopropanol, Au-complex was added under N2, the mixt. was stirred at 50°C for 24 h; rotary evapd., the solid was extd. with benzene, filtered, concd. to dryness, washed with pentane and dried, reextd. into a min benzene, filtered, washed with pentane, the solid was washed with methanol, pentane and dried; elem. anal.;
DOI:10.1016/j.jorganchem.2008.11.054
- Guidance literature:
-
In
tetrahydrofuran;
3-methoxyphenylmagnesium bromide added dropwise at -78°C to soln.ClAuPPh3 in THF in Schlenk techniques under Ar; mixt. warmed to room te mp., mixed for 16 h; treated with satd. soln. of NH4Cl, extd. with Et2O; org. layers washed with satd. soln. of NaCl, dried over MgSO4; solvents removed under vac.; crystals obtained via crystn. from CHCl3;
DOI:10.1016/j.jorganchem.2005.07.080
