Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-

Base Information

• Chemical Name: Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-
• CAS No.: 55290-05-6
• Molecular Formula: C30H28 N2 O2
• Molecular Weight: 448.565
• Hs Code.: 2925290090
• European Community (EC) Number: 259-570-6
• UNII: S8LQZ8QH2R
• DSSTox Substance ID: DTXSID8069010
• Nikkaji Number: J208.085K
• ChEMBL ID: CHEMBL2268782
• Mol file: 55290-05-6.mol

Synonyms:55290-05-6;Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-;N,N'-Bis(4-methoxybenzylidene)-alpha,alpha'-bi-p-toluidine;1-(4-methoxyphenyl)-N-[4-[2-[4-[(4-methoxyphenyl)methylideneamino]phenyl]ethyl]phenyl]methanimine;N,N-BIS(4-METHOXYBENZYLIDENE)-ALPHA,ALPHA-BI-P-TOLUIDINE;Benzenamine, 4,4'-(1,2-ethanediyl)bis(N-((4-methoxyphenyl)methylene)-;4,4'-Ethylenebis(N-(4-methoxybenzylidene)aniline);S8LQZ8QH2R;SCHEMBL2453050;CHEMBL2268782;DTXSID8069010;EINECS 259-570-6;MFCD00041902;FT-0728156;1,2-Bis[4-(4-methoxybenzylideneamino)phenyl]ethane;Bis(p-methoxybenzylidene)-.alpha.,.alpha.'-bi-p-toluidine;N,N'-Bis(p-methoxybenzylidene)-alpha,alpha'-bi-p-toluidine;N,N'-Bis(p-methoxy-benzylidene)-.alpha.-.alpha.'-bi-p-toluidine;(NE,N'E)-4,4'-(ethane-1,2-diyl)bis(N-(4-methoxybenzylidene)aniline);4,4'-(1,2-Ethanediyl)bis[N-[(4-methoxyphenyl)methylene]benzenamine];Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-, (E,E)-;Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-, [N(E),N'(E)]-;103445-71-2;N-[(Z)-(4-Methoxyphenyl)methylidene]-N-(4-[2-(4-([(Z)-(4-methoxyphenyl)methylidene]amino)phenyl)ethyl]phenyl)amine #

Chemical Property of Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-

Chemical Property:

• Refractive Index: 1.5800 (estimate)
• Boiling Point: 557.26°C (rough estimate)
• Flash Point: 260.1oC
• PSA: 43.18000
• Density: 1.1404 (rough estimate)
• LogP: 6.99020
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 448.215078140
• Heavy Atom Count: 34
• Complexity: 549

Purity/Quality:

98% ^*data from raw suppliers

N,N'-BIS(4-METHOXYBENZYLIDENE)-ALPHA,ALPHA'-BI-PARA-TOLUIDINE 97.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C=NC2=CC=C(C=C2)CCC3=CC=C(C=C3)N=CC4=CC=C(C=C4)OC

Technology Process of Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]-

There total 2 articles about Benzenamine, 4,4'-(1,2-ethanediyl)bis[N-[(4-methoxyphenyl)methylene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4,4'-diaminodihydrostilbene (621-95-4) + 4-methoxy-benzaldehyde (123-11-5) → N,N'-bis-(4-methoxy-benzylidene)-bibenzyl-4,4'-diyldiamine (55290-05-6)

Guidance literature:

With zinc(II) chloride; In ethanol; Heating;

DOI:10.1021/jf0342324

Reference yield:

1,2-bis(4-nitrophenyl)ethane (736-30-1) → N,N'-bis-(4-methoxy-benzylidene)-bibenzyl-4,4'-diyldiamine (55290-05-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / HCO₂H; Zn / Pd/C

2: 70 percent / ZnCl₂ / ethanol / Heating

With formic acid; zinc(II) chloride; zinc; palladium on activated charcoal; In ethanol;

DOI:10.1021/jf0342324

Reference yield: 87.0%

N,N'-bis-(4-methoxy-benzylidene)-bibenzyl-4,4'-diyldiamine (55290-05-6) + 2-mercaptopropanoic acid (79-42-5) → C36H36N2O4S2

Guidance literature:

In benzene; Heating;

DOI:10.1021/jf0342324

upstream raw materials:

4,4'-diaminodihydrostilbene

4-methoxy-benzaldehyde

1,2-bis(4-nitrophenyl)ethane

Refernces