9H-Thioxanthenium, 10-methyl-9-(2,4,6-trimethylphenyl)-, trans-,perchlorate

Base Information

• Chemical Name: 9H-Thioxanthenium, 10-methyl-9-(2,4,6-trimethylphenyl)-, trans-,perchlorate
• CAS No.: 90133-33-8
• Molecular Formula: C23H23S.ClO4
• Molecular Weight: 430.952
• Mol file: 90133-33-8.mol

Synonyms:

Chemical Property of 9H-Thioxanthenium, 10-methyl-9-(2,4,6-trimethylphenyl)-, trans-,perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9H-Thioxanthenium, 10-methyl-9-(2,4,6-trimethylphenyl)-, trans-,perchlorate

There total 4 articles about 9H-Thioxanthenium, 10-methyl-9-(2,4,6-trimethylphenyl)-, trans-,perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

9-mesitylthioxanthene (53512-25-7) + methyl iodide (74-88-4) → 10-methyl-9-(2,4,6-trimethylphenyl)thioxanthenium perchlorate3 (90133-33-8)

Guidance literature:

With silver perchlorate; In 1,2-dichloro-ethane;

DOI:10.1021/jo00191a020 DOI:10.1021/jo00187a033

Reference yield:

2-(phenylthio)benzaldehyde (36943-39-2) → 10-methyl-9-(2,4,6-trimethylphenyl)thioxanthenium perchlorate3 (90133-33-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 90 percent / Mg, (I₂) / diethyl ether / 3 h / Heating

2: 95 percent / H₂SO₄ (80percent) / 0.5 h / Heating

3: 94 percent / AgClO₄ / 1,2-dichloro-ethane

With sulfuric acid; iodine; silver perchlorate; magnesium; In diethyl ether; 1,2-dichloro-ethane;

DOI:10.1021/jo00187a033

Reference yield:

2-chloro-benzaldehyde (89-98-5) → 10-methyl-9-(2,4,6-trimethylphenyl)thioxanthenium perchlorate3 (90133-33-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 90 percent / Na₂CO₃, hexamethylphosphoramide (HMPA) / 5 h / 80 - 90 °C

2: 90 percent / Mg, (I₂) / diethyl ether / 3 h / Heating

3: 95 percent / H₂SO₄ (80percent) / 0.5 h / Heating

4: 94 percent / AgClO₄ / 1,2-dichloro-ethane

With N,N,N,N,N,N-hexamethylphosphoric triamide; sulfuric acid; iodine; silver perchlorate; sodium carbonate; magnesium; In diethyl ether; 1,2-dichloro-ethane;

DOI:10.1021/jo00187a033

upstream raw materials:

9-mesitylthioxanthene

methyl iodide

2-(phenylthio)benzaldehyde

2-chloro-benzaldehyde

Downstream raw materials:

3-methyl-(2,4,6-trimethylphenyl)thioxanthene

3,6-dimethyl-9-mesitylthioxanthene

3,10-dimethyl-9-(2,4,6-trimethylphenyl)thioxanthenium perchlorate

3,10-dimethyl-(2,4,6-trimethylphenyl)thioxanthenium perchlorate