Ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Base Information

Chemical Name:Ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate
CAS No.:90401-85-7
Molecular Formula:C13H14O3
Molecular Weight:218.24800
Hs Code.:2918300090
DSSTox Substance ID:DTXSID10544869
Wikidata:Q82422163
Mol file:90401-85-7.mol

Synonyms:ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate;90401-85-7;ETHYL 5-OXO-7,8-DIHYDRO-6H-NAPHTHALENE-2-CARBOXYLATE;2-Naphthalenecarboxylic acid, 5,6,7,8-tetrahydro-5-oxo-, ethyl ester;SCHEMBL552474;Ethyl5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate;DTXSID10544869;XNXPDMGFXHBLHK-UHFFFAOYSA-N;J-521156;ethyl 5-oxo-5,6,7,8-tetrahydro-2-naphthalenecarboxylate

Suppliers and Price of Ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Chemenu
ethyl5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate 95%
1g
$ 282.00

American Custom Chemicals Corporation
ETHYL-5-OXO-5,6,7,8-TETRAHYDRONAPHTHALENE-2-CARBOXYLATE 95.00%
5MG
$ 499.83

Alichem
Ethyl5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate
1g
$ 400.00

Total 6 raw suppliers

Chemical Property of Ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Chemical Property:

PSA：43.37000
LogP:2.38230
Storage Temp.:2-8°C
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:218.094294304
Heavy Atom Count:16
Complexity:285

Purity/Quality:

98% ^*data from raw suppliers

ethyl5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CC2=C(C=C1)C(=O)CCC2

Technology Process of Ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

There total 3 articles about Ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 3470-46-0
5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid

: 64-17-5
ethanol

: 90401-85-7
ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Guidance literature:: With hydrogenchloride; for 3h; Heating;
DOI:10.1248/cpb.32.130

Reference yield:

: 3470-53-9
6-amino-1-tetralone

: 90401-85-7
ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 62 percent / NaNO₂, CuSO₄ / H₂O; aq. HCl / 2 h / 0 °C

2: 38 percent / KOH / ethanol; H₂O / 4 h / Heating

3: 62 percent / HCl (20percent) / 3 h / Heating

With hydrogenchloride; potassium hydroxide; copper(II) sulfate; sodium nitrite; In hydrogenchloride; ethanol; water;
DOI:10.1248/cpb.32.130

Reference yield:

: 90401-84-6
6-cyano-1-tetralone

: 90401-85-7
ethyl 5-oxo-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 38 percent / KOH / ethanol; H₂O / 4 h / Heating

2: 62 percent / HCl (20percent) / 3 h / Heating

With hydrogenchloride; potassium hydroxide; In ethanol; water;
DOI:10.1248/cpb.32.130