Lithium aluminate

Base Information

• Chemical Name: Lithium aluminate
• CAS No.: 12003-67-7
• Deprecated CAS: 1224469-02-6,1228825-21-5,1257527-02-8,1331756-53-6,2218487-45-5,2270880-22-1,2664845-89-8
• Molecular Formula: AlLiO₂
• Molecular Weight: 65.9213
• Hs Code.: 2841908590
• European Community (EC) Number: 234-434-9
• Wikipedia: Lithium aluminate
• Wikidata: Q2190661
• Mol file: 12003-67-7.mol

Synonyms:LiAl(O2);lithium aluminate

Chemical Property of Lithium aluminate

Chemical Property:

• Appearance/Colour: colorless orthorhombic crystal
• Melting Point: >1625°C
• PSA: 40.13000
• Density: 2.615 g/mL at 25 °C(lit.)
• LogP: -0.12510
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 65.9873711
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lithium aluminate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Li+].[O-][Al]=O
• Uses: It is?used as an inert?electrolyte?support material in molten?carbonate?fuel cells.

Technology Process of Lithium aluminate

There total 103 articles about Lithium aluminate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3) → lithium aluminate (12003-67-7) + phosphorus hydride (13967-14-1) + lithium tetrachloroaluminate + hydrogen (1333-74-0) + phosphan (7803-51-2)

Guidance literature:

In diethyl ether; react. with LiAlH4 in ether at -115 °C; react. of POCl3 with LiAlH4 forming PH3, LiAlCl4, LiAlO2 and H2 and react. forming PH, LiAlCl4, LiAlO2 and H2;;

Reference yield:

aluminium hydride + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3) → lithium aluminate (12003-67-7) + phosphorus hydride (13967-14-1) + lithium tetrachloroaluminate + hydrogen (1333-74-0) + phosphan (7803-51-2)

Guidance literature:

In diethyl ether; react. with AlH3 in ether at -115 °C;;

Reference yield:

AlLi5O4, β, high temperature + water (7732-18-5) → lithium aluminate (12003-67-7) + lithium hydroxide (1310-65-2)

Guidance literature:

moist atmosphere;

DOI:10.1016/0022-4596(87)90154-X

upstream raw materials:

aluminum oxide

lithium fluoride

lithium aluminium tetrahydride

water

Refernces

• 1、 Ribeiro,Silva,Mohallem. "The influences of heat treatment on the structural properties of lithium aluminates". . p. 857 - 864. Retrieved 2001.
• 2、 Pavel,Zvoianu,B?rjega,Angelescu. "Impact of the memory effect on the catalytic activity of Li-Al hydrotalcite-like compounds for the cyanoethylation reaction". . p. 1106 - 1111. Retrieved 2010.
• 3、 Stoyanova, Radostina,Zhecheva, Ekaterina,Alcántara, Ricardo,Tirado, José L.. "Local Coordination of Low-Spin Ni3+ Probes in Trigonal LiAl yCo1-yO2 Monitored by HF-EPR". . p. 4053 - 4057. Retrieved 2004.
• 4、 Iano?, Robert,Laz?u, Ioan,P?curariu, Cornelia. "Metal nitrate/fuel mixture reactivity and its influence on the solution combustion synthesis of γ-LiAlO2". . p. 209 - 214. Retrieved 2009.
• 5、 Valenzuela, Miguel A.,Jimenez-Becerril, Jaime,Bosch, Pedro,Bulbulian, Silvia,Lara, Victor H.. "Sol-gel synthesis of lithium aluminate". . p. 455 - 460. Retrieved 1996.
• 6、 Watanabe,Takeuchi,Saeki. "CRYSTAL GROWTH OF ROD-SHAPED beta -LiAlO2.". . p. c. 268-c. 269. Retrieved 1987.
• 7、 Hou,Kirkpatrick. "Thermal evolution of the CI--LiAl2 layered double hydroxide: A multinuclear MAS NMR and XRD perspective". . p. 6397 - 6404. Retrieved 2001.
• 8、 Konishi,Ohno. "ELECTRICAL CONDUCTIVITY OF POLYCRYSTALLINE Li2SiO3 AND gamma -LiAlO2.". . p. 418 - 419. Retrieved 1984.
• 9、 Watanabe,Takeuchi,Saeki. "Effect of Al(OH)3 addition on β-LiAlO2 crystal growth". . p. 3094 - 3095. Retrieved 1990.
• 10、 Li, Fanqun,Qin, Furong,Wang, Guanchao,Zhang, Kai,Wang, Peng,Zhang, Zhian,Lai, Yanqing. "A LiAlO2/nitrogen-doped hollow carbon spheres (NdHCSs) modified separator for advanced lithium-sulfur batteries". . p. 1632 - 1637. Retrieved 2018.