(6Z)-6-[(hydroxyamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)

Base Information

• Chemical Name: (6Z)-6-[(hydroxyamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)
• CAS No.: 14363-26-9
• Molecular Formula: C₁₄H₁₂CuN₂O₄
• Molecular Weight: 335.806
• Mol file: 14363-26-9.mol

Synonyms:Copper,bis(2-hydroxybenzaldehyde oximato-N1,O2)-; Copper, bis(salicylaldehydeoximato)- (6CI,7CI,8CI); Benzaldehyde, 2-hydroxy-, oxime, copper complex;Bis(salicylaldehyde oximato)copper; Bis(salicylaldoximato)copper; Copper(II)salicylaldoximate; NSC 166010

Chemical Property of (6Z)-6-[(hydroxyamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)

Chemical Property:

• Vapor Pressure: 0.000162mmHg at 25°C
• Boiling Point: 295.1°Cat760mmHg
• Flash Point: 132.3°C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (6Z)-6-[(hydroxyamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1)

There total 12 articles about (6Z)-6-[(hydroxyamino)methylidene]cyclohexa-2,4-dien-1-one - copper (2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

salicylaldehyde-oxime (94-67-7) + copper(II) acetate monohydrate (6046-93-1) → trans-bis(salicylaldoximato)copper(II) (41942-15-8,14363-26-9)

Guidance literature:

In ethanol; acetic acid; addn. of a soln. of salicylaldoxime in EtOH to a soln. of Cu acetate indilute acetic acid; recrystn. from EtOH, elem. anal.;

Reference yield: 74.55%

copper(II) choride dihydrate + salicylaldehyde-oxime (94-67-7) → bis(salicylaldoximato)copper(II) (14363-26-9,41942-15-8)

Guidance literature:

With potassium hydroxide; In ethanol; Reflux;

DOI:10.13005/ojc/320620

Reference yield: 74.0%

salicylaldehyde-oxime (94-67-7) + copper dichloride → trans-bis(salicylaldoximato)copper(II) (41942-15-8,14363-26-9)

Guidance literature:

With hydrochloric acid; In ethanol; water; addn. of an slightly acidified aq. soln. of CuCl2 to an ethanolic soln. of the oxime with stirring; filtration, recrystn. from chloroform/ether, elem. anal.;

DOI:10.1016/S0277-5387(00)86011-8

upstream raw materials:

salicylaldehyde-oxime

copper(II) acetate monohydrate

copper(II) sulfate

bis(N-salicylaldimino) Cu(II)

Downstream raw materials:

Cu(o-hydroxybenzaldoxime)

Refernces

• 1、 Lazarou, Katerina N.,Boudalis, Athanassios K.,Psycharis, Vassilis,Raptopoulou, Catherine P.. "Copper(II)-mediated oxime-nitrile coupling in non-aqueous solutions: Synthetic, structural and magnetic studies of the copper(II)-salicylaldehyde oxime reaction system". . p. 50 - 58. Retrieved 2011.
• 2、 Biradar, N. S.,Karajagi, G. V.,Aminabhavi, T. M.,Rudzinski, W. E.. "". . p. L107 - L110. Retrieved 1983.
• 3、 Dawson, Daniel M.,Ke, Zhipeng,Mack, Frederick M.,Doyle, Rachel A.,Bignami, Giulia P. M.,Smellie, Iain A.,Bühl, Michael,Ashbrook, Sharon E.. "Calculation and experimental measurement of paramagnetic NMR parameters of phenolic oximate Cu(II) complexes". supporting information. p. 10512 - 10515. Retrieved 2017/09/29.