alpha-D-Glucopyranose, 1-thio-, pentaacetate

Base Information

Chemical Name:alpha-D-Glucopyranose, 1-thio-, pentaacetate
CAS No.:62860-10-0
Molecular Formula:C16H22 O10 S
Molecular Weight:406.411
Hs Code.:
DSSTox Substance ID:DTXSID801228524
Nikkaji Number:J429.498J
Wikidata:Q76009767
Mol file:62860-10-0.mol

Synonyms:62860-10-0;1-Thio-alpha-D-glucopyranose pentaacetate;alpha-D-Glucopyranose, 1-thio-, pentaacetate;[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-acetylsulfanyloxan-2-yl]methyl acetate;alpha-D-Glucopyranose, 1-thio-, 1,2,3,4,6-pentaacetate;ALPHA-D-PENTAACETATETHIO GLUCOPYRANOSE;C16-H22-O10-S;.alpha.-D-Glucopyranose, 1-thio-, pentaacetate;SCHEMBL9162738;DTXSID801228524;(2R,3R,4S,5R,6R)-2-(Acetoxymethyl)-6-(acetylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate;[(2R,3R,4S,5R,6R)-3,4,5-TRIS(ACETYLOXY)-6-(ACETYLSULFANYL)OXAN-2-YL]METHYL ACETATE

Suppliers and Price of alpha-D-Glucopyranose, 1-thio-, pentaacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 22 raw suppliers

Chemical Property of alpha-D-Glucopyranose, 1-thio-, pentaacetate

Chemical Property:

Vapor Pressure:6.17E-09mmHg at 25°C
Melting Point:121-122 °C
Boiling Point:468.1°Cat760mmHg
Flash Point:222.3°C
PSA：156.80000
Density:1.32g/cm³
LogP:0.34920
XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:11
Rotatable Bond Count:11
Exact Mass:406.09336807
Heavy Atom Count:27
Complexity:604

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)SC(=O)C)OC(=O)C)OC(=O)C)OC(=O)C
Isomeric SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)SC(=O)C)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of alpha-D-Glucopyranose, 1-thio-, pentaacetate

There total 37 articles about alpha-D-Glucopyranose, 1-thio-, pentaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 10387-40-3
potassium thioacetate

: 6806-56-0,13639-50-4,51898-27-2,62860-10-0,63783-77-7,92217-67-9,92217-68-0,130796-15-5
O²,O³,O⁴,O⁶,S-Pentaacetyl-1-thio-β-D-glucopyranose

Guidance literature:: for 2h; Neat (no solvent); Ball milling;
DOI:10.1039/b904454j

Reference yield: 97.0%

: 507-09-5
tiolacetic acid

: 604-69-3
β-D-glucose pentaacetate

: 6806-56-0,13639-50-4,51898-27-2,62860-10-0,63783-77-7,92217-67-9,92217-68-0,130796-15-5
O²,O³,O⁴,O⁶,S-Pentaacetyl-1-thio-β-D-glucopyranose

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 0 - 30 ℃; for 3.5h; stereoselective reaction; Inert atmosphere;
DOI:10.1039/d0ob01956a

Reference yield: 95.0%

: 10387-40-3
potassium thioacetate

: 604-69-3
β-D-glucose pentaacetate

: 6806-56-0,13639-50-4,51898-27-2,62860-10-0,63783-77-7,92217-67-9,92217-68-0,130796-15-5
O²,O³,O⁴,O⁶,S-Pentaacetyl-1-thio-β-D-glucopyranose

Guidance literature:: With boron trifluoride diethyl etherate; In ethyl acetate; at 50 ℃; for 4h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; Schlenk technique;
DOI:10.1002/ejoc.202100357