Iodine monofluoride

Base Information

• Chemical Name: Iodine monofluoride
• CAS No.: 13873-84-2
• Molecular Formula: FI
• Molecular Weight: 145.903
• DSSTox Substance ID: DTXSID50160764
• Nikkaji Number: J148.100B
• Wikipedia: Iodine monofluoride
• Wikidata: Q419914
• Mol file: 13873-84-2.mol

Synonyms:Iodine monofluoride;13873-84-2;fluoroiodide;Fluorine iodide;fluoride-iodonium;Iodine fluoride (IF);DTXSID50160764;Q419914;F-I;I-F

Chemical Property of Iodine monofluoride

Chemical Property:

• Melting Point: -14℃ [CRC10]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 2.762g/cm³
• LogP: 1.30590
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 145.90288
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: FI

Technology Process of Iodine monofluoride

There total 5 articles about Iodine monofluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorine trifluoride (7790-91-2) + iodine (7553-56-2,12190-71-5,8031-47-8) → iodine pentafluoride (676353-70-1,51096-45-8,7783-66-6) + iodine monofluoride (13873-84-2)

Guidance literature:

In neat (no solvent);

Reference yield:

bismuth(III) iodide (7787-64-6) + fluorine → bismuth(III) fluoride (7787-61-3) + iodine monofluoride (13873-84-2)

Guidance literature:

In gas; admitting F atoms (from an inlet tube) and iodide (from a heated glass crucible) to a blackened Al cell under reduced pressure;; detn. by visible chemiluminiscence in the range of 425-800nm (emitter IF);;

DOI:10.1039/F29878300767

Reference yield:

tetrafluoro-trifluoromethyl-λ5-iodane (38091-67-7) → carbon tetrafluoride (75-73-0) + iodotrifluoromethane (2314-97-8,263005-66-9) + iodine pentafluoride + iodine monofluoride (13873-84-2) + IF3 (22520-96-3)

Guidance literature:

byproducts: I2;

DOI:10.1039/DT9740000119

upstream raw materials:

chlorine trifluoride

iodine

lithium iodide

bismuth(III) iodide

Downstream raw materials:

4-fluoro-1-iodobenzene

(dcpe)Pt(II)F₂

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