H2ATSM/A

Base Information

• Chemical Name: H2ATSM/A
• CAS No.: 918879-58-0
• Molecular Formula: C7H15N7S2
• Molecular Weight: 261.375
• Mol file: 918879-58-0.mol

Synonyms:Diacetyl-2-(4-N-methyl-3-thiosemicarbazone)-3-(4-N-amino-3-thiosemicarbazone);Carbonothioic dihydrazide 2-[1-methyl-2-[2-[(methylamino)thioxomethyl] hydrazinyliden propylidene]-;

Chemical Property of H2ATSM/A

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of H2ATSM/A

There total 1 articles about H2ATSM/A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diacetyl-2-(4-N-methyl-3-thiosemicarbazone) (126971-40-2,149096-41-3) + Thiocarbohydrazide (2231-57-4) → diacetyl-2-(4-N-methyl-3-thiosemicarbazone)-3-(4-N-amino-3-thiosemicarbazone) (918879-58-0)

Guidance literature:

With hydrogenchloride; In ethanol; water; for 5h; Reflux;

DOI:10.1039/c5ra06437f

Reference yield: 97.0%

methanol (67-56-1) + diacetyl-2-(4-N-methyl-3-thiosemicarbazone)-3-(4-N-amino-3-thiosemicarbazone) (918879-58-0) + zinc(II) acetate dihydrate (5970-45-6) → diacetyl-2-(4-N-methyl-3-thiosemicarbazonato)-3-(4-N-amino-3-thiosemicarbazonato)zinc(II) monomethanol

Guidance literature:

In methanol; Zn-contg. compd. (6.5 mmol) was added to a ligand (5.4 mmol) in MeOH; the mixt. was heated under reflux for 4 h; after cooling, the ppt. was collected by filtration, washed with methanol, diethyl ether, and dried in vac. at 80°C; elem. anal.;

DOI:10.1021/ic0615628

Reference yield: 84.0%

diacetyl-2-(4-N-methyl-3-thiosemicarbazone)-3-(4-N-amino-3-thiosemicarbazone) (918879-58-0) + C10H10N4O6 (1350306-03-4) → C13H20N10O3S2 (1208998-89-3)

Guidance literature:

With triethylamine; In dimethyl sulfoxide; for 6h;

DOI:10.1016/j.jinorgbio.2009.10.009

upstream raw materials:

diacetyl-2-(4-N-methyl-3-thiosemicarbazone)

Thiocarbohydrazide

Downstream raw materials:

diacetyl-2-(4-N-methyl-3-thiosemicarbazone)-3-(4-N-amino-(4-fluorobenzylamide)-3-thiosemicarbazone)

C₁₃H₂₀N₁₀O₃S₂

C₁₀H₁₉N₇OS₂

C₁₃H₂₀N₁₀O₃S₂