N,N-dibutyl-5,6,12,13-tetrakis(4-(1,1-dimethylethyl)phenoxy)- 3,4,9,10-perylenedicarboximide

Base Information

• Chemical Name: N,N-dibutyl-5,6,12,13-tetrakis(4-(1,1-dimethylethyl)phenoxy)- 3,4,9,10-perylenedicarboximide
• CAS No.: 335654-34-7
• Molecular Formula: C72H74N2O8
• Molecular Weight: 1095.39
• Mol file: 335654-34-7.mol

Synonyms:N,N-dibutyl-5,6,12,13-tetrakis(4-(1,1-dimethylethyl)phenoxy)- 3,4,9,10-perylenedicarboximide

Chemical Property of N,N-dibutyl-5,6,12,13-tetrakis(4-(1,1-dimethylethyl)phenoxy)- 3,4,9,10-perylenedicarboximide

Chemical Property:

• PKA: -2.61±0.20(Predicted)
• PSA: 115.06000
• Density: 1.200±0.06 g/cm3(Predicted)
• LogP: 17.92240

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-dibutyl-5,6,12,13-tetrakis(4-(1,1-dimethylethyl)phenoxy)- 3,4,9,10-perylenedicarboximide

There total 2 articles about N,N-dibutyl-5,6,12,13-tetrakis(4-(1,1-dimethylethyl)phenoxy)- 3,4,9,10-perylenedicarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

para-tert-butylphenol (98-54-4) + N,N’-dibutyl-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide (95689-64-8) → N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (335654-34-7)

Guidance literature:

With 1-methyl-pyrrolidin-2-one; potassium carbonate; at 140 ℃; for 8h;

DOI:10.1021/jo011133l

Reference yield:

1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride (156028-26-1) → N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (335654-34-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 84 percent / propionic acid / 8 h / 140 °C

2: 56 percent / potassium carbonate; 1-methyl-2-pyrrolidinone / 8 h / 140 °C

With 1-methyl-pyrrolidin-2-one; potassium carbonate; propionic acid;

DOI:10.1021/jo011133l

Reference yield: 95.0%

N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (335654-34-7) → 1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride (156028-30-7)

Guidance literature:

With potassium hydroxide; In tert-butyl alcohol; at 80 ℃; for 10h;

DOI:10.1002/1521-3765(20001103)6:21<3871::AID-CHEM3871>3.3.CO;2-W

upstream raw materials:

para-tert-butylphenol

N,N’-dibutyl-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Downstream raw materials:

1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride

N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

C₇₈H₈₃N₃O₁₀

N-n-butyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4-dicarboxylate anhydride-9,10-dicarboxylate imide