1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride

Base Information

• Chemical Name: 1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride
• CAS No.: 156028-30-7
• Molecular Formula: C64H56 O10
• Molecular Weight: 985.143
• European Community (EC) Number: 863-475-0
• Nikkaji Number: J1.850.784F
• Mol file: 156028-30-7.mol

Synonyms:156028-30-7;1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride;11,14,22,26-tetrakis(4-tert-butylphenoxy)-7,18-dioxaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone;5,6,12,13-tetrakis(4-(tert-butyl)phenoxy)anthra[2,1,9-def:6,5,10-d'e'f']diisochromene-1,3,8,10-tetraone;Fluorescent Agent-5;SCHEMBL13508264;MFCD09751257;AKOS015901333;1,6,7,12-Tetra-t-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride, tech.

Chemical Property of 1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride

Chemical Property:

• PSA: 123.66000
• Density: 1.276
• LogP: 16.71760
• XLogP3: 17.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 12
• Exact Mass: 984.38734798
• Heavy Atom Count: 74
• Complexity: 1770

Purity/Quality:

99% ^*data from raw suppliers

FluorescentAgent-5 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)C1=CC=C(C=C1)OC2=C3C4=C(C=C5C6=C4C(=C(C=C6C(=O)OC5=O)OC7=CC=C(C=C7)C(C)(C)C)C8=C(C=C9C(=C38)C(=C2)C(=O)OC9=O)OC1=CC=C(C=C1)C(C)(C)C)OC1=CC=C(C=C1)C(C)(C)C
• Uses: Fluorescent agent-5 is a fluorescent compound used in the preparation of perylene bisimide cyclophane for use as a fluorescent probe. Fluorescent agent-5 also features as a ligand in bis(terpyridine)-ruthenium complexes with photovoltaic properties for use in dye-?sensitized solar cells.

Technology Process of 1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride

There total 12 articles about 1,6,7,12-Tetra-tert-butylphenoxyperylene-3,4,9,10-tetracarboxylic dianhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N,N'-dioctyl-1,6,7,12-tetrakis(4-t-butylphenoxy)perylene-3,4,9,10-tetracarboxylic acid diimide → 1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride (156028-30-7)

Guidance literature:

With potassium hydroxide; In isopropyl alcohol; Inert atmosphere; Reflux;

DOI:10.1039/c2cc33120a

Reference yield: 95.0%

N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (335654-34-7) → 1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride (156028-30-7)

Guidance literature:

With potassium hydroxide; In tert-butyl alcohol; at 80 ℃; for 10h;

DOI:10.1002/1521-3765(20001103)6:21<3871::AID-CHEM3871>3.3.CO;2-W

Reference yield: 93.0%

N,N'-dipentyl-1,6,7,12-tetra(p-tert-butylphenoxy)perylene-3,4:9,10-bis(dicarboximide) (949572-56-9) → 1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride (156028-30-7)

Guidance literature:

With lithium hydroxide; In tert-butyl alcohol; Reflux;

DOI:10.1002/chem.200800156

upstream raw materials:

N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

N,N'-dipentyl-1,6,7,12-tetra(p-tert-butylphenoxy)perylene-3,4:9,10-bis(dicarboximide)

N,N'-bis-n-propyl-1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxdiimide

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

Downstream raw materials:

N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

N,N'-(3,5-(piperidine-1-carbonyl)-phenyl)-1,6,7,12-tetrakis-[4'-tert-butylphenoxy]-3,4:9,10-perylenetetracarboxylic diimide

N,N'-(3,5-bis{4-[2-(7-methoxy-2-oxo-2H-chromen-3-yl)acetyl]piperazine-1-carbonyl}phenyl)-1,6,7,12-tetrakis[4'-tert-butylphenoxy]-3,4:9,10-perylenetetracarboxylic diimide