N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

Base Information

• Chemical Name: N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide
• CAS No.: 266678-68-6
• Molecular Formula: C₇₄H₆₄N₄O₈
• Molecular Weight: 1137.34
• Mol file: 266678-68-6.mol

Synonyms:N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property of N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

There total 2 articles about N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

4-aminopyridine (504-24-5) + 1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride (156028-30-7) → N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (266678-68-6)

Guidance literature:

With quinoline; zinc diacetate; at 180 ℃; for 16h;

DOI:10.1002/1521-3765(20010216)7:4<894::AID-CHEM894>3.0.CO;2-N

Reference yield:

4-aminopyridine (504-24-5) + N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (335654-34-7) → N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (266678-68-6) + N-(4-Pyridyl)-N'-butyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide

Guidance literature:

N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide; With potassium hydroxide; In isopropyl alcohol; for 15h; Heating;

4-aminopyridine; With quinoline; zinc diacetate; at 180 ℃; for 16h; Further stages.;

DOI:10.1002/1521-3765(20010216)7:4<894::AID-CHEM894>3.0.CO;2-N

Reference yield: 90.0%

(meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II) (41654-56-2) + N,N'-Di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide (266678-68-6) → (N,N'-di(4-pyridyl)-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide)[Ru(5,10,15,20-tetraphenylporphyrinato)(CO)]2

Guidance literature:

In chloroform; ligand added to a suspn. of complex, reacted overnight at room temp.; pptd. from the concd. soln. with n-hexane, filtered, washed (cold MeOH, n-hexane), dried (vac.);

DOI:10.1021/ja045379u

upstream raw materials:

4-aminopyridine

1,6,7,12-tetrakis(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid dianhydride

N,N'-dibutyl-1,6,7,12-tetra(4-tert-butylphenoxy)perylene-3,4:9,10-tetracarboxylic acid bisimide