Methyl N-methoxybenzenecarboximidoate

Base Information

• Chemical Name: Methyl N-methoxybenzenecarboximidoate
• CAS No.: 41071-39-0
• Molecular Formula: C9H11NO2
• Molecular Weight: 165.192
• Mol file: 41071-39-0.mol

Synonyms:Benzenecarboximidic acid, N-methoxy-, methyl ester;N-Methoxy-benzimidic acid methyl ester;N,1-Dimethoxy-1-phenyl-methanimine;

Chemical Property of Methyl N-methoxybenzenecarboximidoate

Chemical Property:

• Vapor Pressure: 0.288mmHg at 25°C
• Refractive Index: 1.481
• Boiling Point: 209.8 °C at 760 mmHg
• Flash Point: 69 °C
• Density: 1 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl N-methoxybenzenecarboximidoate

There total 15 articles about Methyl N-methoxybenzenecarboximidoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + Benzohydroxamic acid (495-18-1) → N-methoxy-N-methylbenzamide (6919-61-5) + Methyl (Z)-O-Methylbenzohydroximate (41071-39-0) + Methyl (Z)-Benzohydroximate (68525-46-2)

Guidance literature:

In diethyl ether; at 20 ℃; for 24h; Product distribution;

DOI:10.1021/jo0012391

Reference yield: 60.0%

methanol (67-56-1) + (Z)-N-methoxybenzenecarboximidoyl chloride (41071-35-6) → Methyl (Z)-O-Methylbenzohydroximate (41071-39-0)

Guidance literature:

methanol; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; for 3h; Inert atmosphere;

(Z)-N-methoxybenzenecarboximidoyl chloride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/jacs.8b07578

Reference yield: 36.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + Benzohydroxamic acid (495-18-1) → benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) + 3,4-diphenyl-1,2,4-oxadiazol-5(4H)-one (14562-01-7) + Methyl (E)-O-Methylbenzohydroximate (41071-40-3) + Methyl (Z)-O-Methylbenzohydroximate (41071-39-0)

Guidance literature:

diazomethane; Benzohydroxamic acid; In diethyl ether; at 20 ℃; for 24h;

at 150 ℃; for 24h;

DOI:10.1021/jo0012391

upstream raw materials:

methanol

(Z)-N-methoxybenzenecarboximidoyl chloride

(E)-O-methylbenzohydroximoyl chloride

sodium methylate

Downstream raw materials:

Ethyl (Z)-O-Methylbenzohydroximate

Methyl (E)-O-Methylbenzohydroximate