41071-35-6Relevant articles and documents
Catalytic Alkene Difunctionalization via Imidate Radicals
Nakafuku, Kohki M.,Fosu, Stacy C.,Nagib, David A.
, p. 11202 - 11205 (2018/09/12)
The first catalytic strategy to harness imidate radicals has been developed. This approach enables alkene difunctionalization of allyl alcohols by photocatalytic reduction of their oxime imidates. The ensuing imidate radicals undergo consecutive intra- and intermolecular reactions to afford (i) hydroamination, (ii) aminoalkylation, or (iii) aminoarylation, via three distinct radical mechanisms. The broad scope and utility of this catalytic method for imidate radical reactivity is presented, along with comparisons to other N-centered radicals and complementary, closed-shell imidate pathways.
Mechanisms of acid-catalyzed Z/E isomerization of imines
Johnson, James E.,Morales, Nora M.,Gorczyca, Andrea M.,Dolliver, Debra D.,McAllister, Michael A.
, p. 7979 - 7985 (2007/10/03)
The kinetics and mechanism of acid-catalyzed Z/E isomerization of O-methylbenzohydroximoyl chloride (1Za and 1Ea), methyl O-methylbenzohydroximate (1Zb and 1Eb), ethyl O-methylbenzohydroximate (1Zc and 1Ec and five para and meta substituted derivatives),
Mechamism of an Acid-Catalyzed Geometric Isomerization about a Carbon-Nitrogen Double Bond
Johnson, James E.,Silk, Nancy M.,Nalley, Elizabeth Ann,Arfan, Mohammed
, p. 546 - 552 (2007/10/02)
The mechanism of the hydrogen chloride catalyzed geometric isomerization of (E)-O-methylbenzohydroximoyl chloride (1a) has been investigated.It has been determined that radioactive chloride (36Cl(1-)) is incorporated into the hydroximoyl chloride at a rat
