ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate

Base Information

Chemical Name:ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate
CAS No.:1114966-47-0
Molecular Formula:C13H17ClN2O4
Molecular Weight:300.73808
Hs Code.:2933399090
Mol file:1114966-47-0.mol

Synonyms:ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate

Suppliers and Price of ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Ethyl6-(tert-Butoxycarbonylamino)-4-chloropicolinate
100mg
$ 230.00

TRC
Ethyl6-(tert-Butoxycarbonylamino)-4-chloropicolinate
50mg
$ 120.00

Crysdot
Ethyl6-((tert-butoxycarbonyl)amino)-4-chloropicolinate 95+%
1g
$ 589.00

Chemenu
ethyl6-((tert-butoxycarbonyl)amino)-4-chloropicolinate 95%
1g
$ 557.00

American Custom Chemicals Corporation
ETHYL-6-((TERT-BUTOXYCARBONYL)AMINO)-4-CHLOROPICOLINATE 95.00%
5MG
$ 498.78

Alichem
Ethyl6-((tert-butoxycarbonyl)amino)-4-chloropicolinate
1g
$ 518.40

Total 7 raw suppliers

Chemical Property of ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate

Chemical Property:

PSA：77.52000
LogP:3.33170
Storage Temp.:2-8°C

Purity/Quality:

97% ^*data from raw suppliers

Ethyl6-(tert-Butoxycarbonylamino)-4-chloropicolinate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Ethyl 6-(tert-Butoxycarbonylamino)-4-chloropicolinate is an intermediate used to prepare tetrazoyloxime derivatives as plant disease control agent.

Technology Process of ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate

There total 2 articles about ethyl 6-(tert-butoxycarbonylamino)-4-chloropicolinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1114966-45-8
monoethyl 4-chloro-2,6-pyridinedicarboxylate

: 75-65-0
tert-butyl alcohol

: 1114966-47-0
ethyl 6-(t-butoxycarbonyl)amino-4-chloropicolinate

Guidance literature:: monoethyl 4-chloro-2,6-pyridinedicarboxylate; With diphenyl phosphoryl azide; triethylamine; In tetrahydrofuran; at 20 - 60 ℃;

tert-butyl alcohol; In tetrahydrofuran; at 60 ℃; for 18h;

Reference yield:

: 53389-01-8
diethyl 4-chloropyridine-2,6-dicarboxylate

: 1114966-47-0
ethyl 6-(t-butoxycarbonyl)amino-4-chloropicolinate

Guidance literature:: Multi-step reaction with 2 steps

1.1: water; sodium hydroxide / ethanol / 20 - 55 °C

1.2: pH 2.5

2.1: diphenyl phosphoryl azide; triethylamine / tetrahydrofuran / 20 - 60 °C

2.2: 18 h / 60 °C

With diphenyl phosphoryl azide; water; triethylamine; sodium hydroxide; In tetrahydrofuran; ethanol;

Reference yield:

: 1114966-47-0
ethyl 6-(t-butoxycarbonyl)amino-4-chloropicolinate

: 1114924-91-2
(Z)-(1-methyl-1H-tetrazol-5-yl)phenylmethanone-O-[2-(t-butoxycarbonyl)amino-4-chloropyridin-6-ylmethyl]-oxime

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium tetrahydroborate; ethanol / 17 h / 20 °C

2.1: pyridine; thionyl chloride / dichloromethane / 3.5 h / 20 °C

3.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / Ice cooling

3.2: 3 h / 20 °C

With pyridine; sodium tetrahydroborate; thionyl chloride; ethanol; sodium hydride; In dichloromethane; N,N-dimethyl-formamide; mineral oil;