2-Isopropyladamantan-2-yl methacrylate

Base Information

• Chemical Name: 2-Isopropyladamantan-2-yl methacrylate
• CAS No.: 297156-50-4
• Molecular Formula: C17H26O2
• Molecular Weight: 262.39
• Hs Code.: 2916140000
• European Community (EC) Number: 808-130-7
• DSSTox Substance ID: DTXSID60477496
• Nikkaji Number: J2.597.639H
• Wikidata: Q72485704
• Mol file: 297156-50-4.mol

Synonyms:297156-50-4;2-Isopropyladamantan-2-yl methacrylate;2-isopropyl-2-adamantyl methacrylate;2-Isopropyl-2-methacryloyloxyadamantane;(2-propan-2-yl-2-adamantyl) 2-methylprop-2-enoate;2-(PROPAN-2-YL)ADAMANTAN-2-YL 2-METHYLPROP-2-ENOATE;2-Propenoic acid, 2-methyl-, 2-(1-methylethyl)tricyclo[3.3.1.13,7]dec-2-yl ester;2-Isopropyladamantan-2-ylmethacrylate;Methacrylic Acid 2-Isopropyl-2-adamantyl Ester;SCHEMBL525443;SCHEMBL17805477;SCHEMBL19261612;SCHEMBL19772585;DTXSID60477496;AMY11178;XLA15650;MFCD22571643;AKOS016005145;AC-32097;AS-73738;I0962;F13440;2-ISOPROPYLADAMANTAN-2-YL 2-METHYLPROP-2-ENOATE

Chemical Property of 2-Isopropyladamantan-2-yl methacrylate

Chemical Property:

• Melting Point: 38.0 to 42.0 °C
• Boiling Point: 329.3±11.0 °C(Predicted)
• PSA: 26.30000
• Density: 1.030
• LogP: 3.95660
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 262.193280068
• Heavy Atom Count: 19
• Complexity: 380

Purity/Quality:

2-Isopropyl-2-methacryloyloxyadamantane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1(C2CC3CC(C2)CC1C3)OC(=O)C(=C)C

Technology Process of 2-Isopropyladamantan-2-yl methacrylate

There total 5 articles about 2-Isopropyladamantan-2-yl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-(propan-2-yl)adamantan-2-ol (38432-77-8) + methyl methacrylate (97-63-2,9003-42-3) → 2-isopropyl-2-adamantyl methacrylate (297156-50-4)

Guidance literature:

With sodium methylate; In tetrahydrofuran; at 77 ℃; for 24h;

Reference yield: 97.7%

2-(propan-2-yl)adamantan-2-ol (38432-77-8) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-isopropyl-2-adamantyl methacrylate (297156-50-4)

Guidance literature:

With sodium hydroxide; In butanone; at 79 ℃; for 24h;

Reference yield: 82.0%

2-Adamantanone (700-58-3) + isopropyl chloride (75-29-6) + methacryloyl anhydride (760-93-0) → 2-isopropyl-2-adamantyl methacrylate (297156-50-4)

Guidance literature:

2-Adamantanone; isopropyl chloride; With lithium; In tetrahydrofuran; at 20 ℃; for 2h;

methacryloyl anhydride; In tetrahydrofuran; at 20 ℃; for 1.5h;

upstream raw materials:

2-Adamantanone

isopropyl chloride

methacryloyl anhydride

poly(methacrylic acid)

Downstream raw materials:

C₁₈H₁₅S⁽¹⁺⁾*C₁₉H₂₇F₂O₈S^(1-)

Refernces

• 1、 -. "(Meth) acrylate compound adamantyl". Paragraph 0043-0044. . Retrieved 2019/04/30.
• 2、 -. "(Meth) acrylate hydroxyadamantyl". Paragraph 0063; 0064. . Retrieved 2017/02/09.