Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-

Base Information

Chemical Name:Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-
CAS No.:81846-27-7
Molecular Formula:C₃₈H₆₄O₈SSi
Molecular Weight:709.073
Hs Code.:
Mol file:81846-27-7.mol

Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-

Synonyms:CyclopentaneMethanol, 2-[[3-[[(1,1-diMethylethyl)diMethylsilyl]oxy]phenyl]Methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, Methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-

Suppliers and Price of Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 6 raw suppliers

Chemical Property of Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-

Chemical Property:

PSA：97.90000
LogP:9.88250

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]-

There total 3 articles about Cyclopentanemethanol, 2-[[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]phenyl]methyl]-4-[(tetrahydro-2 H-pyran-2-yl)oxy]-3-[3-[(tetrahydro-2H-pyran-2-yl)oxy]-1-octenyl]-, methanesulfonate, [1S-[1a,2a,3b(1E,3R*),4a]]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 81846-26-6
{(1S,2S,3R,4R)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-benzyl]-4-(tetrahydro-pyran-2-yloxy)-3-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-methanol

: 124-63-0
methanesulfonyl chloride

: 81168-32-3,81203-95-4,81846-02-8,81846-27-7
Methanesulfonic acid (1S,2S,3R,4R)-2-[3-(tert-butyl-dimethyl-silanyloxy)-benzyl]-4-(tetrahydro-pyran-2-yloxy)-3-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentylmethyl ester

Guidance literature:: With triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)87262-7

Reference yield:

: 81846-25-5
tert-Butyl-dimethyl-(3-{(1R,2R,3R)-5-methylene-3-(tetrahydro-pyran-2-yloxy)-2-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentylmethyl}-phenoxy)-silane

: 81168-32-3,81203-95-4,81846-02-8,81846-27-7
Methanesulfonic acid (1S,2S,3R,4R)-2-[3-(tert-butyl-dimethyl-silanyloxy)-benzyl]-4-(tetrahydro-pyran-2-yloxy)-3-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 9-borabicyclo<3.3.1>nonane 2) hydrogen peroxide

2: 88 percent / triethylamine / CH₂Cl₂

With 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)87262-7

Reference yield:

: 65423-57-6
(2R,3R,4R)-2-(3-(tert-butyldimethylsilyloxy)benzyl)-4-(tetrahydro-2H-pyran-2-yloxy)-3-((3S,1E)-3-(tetrahydro-2H-pyran-2-yloxy)oct-1-enyl)cyclopentanone

: 81168-32-3,81203-95-4,81846-02-8,81846-27-7
Methanesulfonic acid (1S,2S,3R,4R)-2-[3-(tert-butyl-dimethyl-silanyloxy)-benzyl]-4-(tetrahydro-pyran-2-yloxy)-3-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 2) aluminum amalgam / 1) THF 2) water-acetic acid-THF (1:1:6)

2: 1) 9-borabicyclo<3.3.1>nonane 2) hydrogen peroxide

3: 88 percent / triethylamine / CH₂Cl₂

With 9-borabicyclo[3.3.1]nonane dimer; aluminium amalgam; dihydrogen peroxide; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)87262-7