Reaction of Enol Silyl Ethers with Silver Carboxylate-Iodine. Synthesis of α-Acyloxy Carbonyl Compounds

DOI: 10.1021/jo00326a023

Source and publish data:

Journal of Organic Chemistry p. 2717 - 2721 (1981)

Update date:2022-09-26

Topics: Iodination

Authors:

Rubottom, George M.

Mott, Robert C.

Juve, Henrik D.

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Article abstract of DOI:10.1021/jo00326a023

The sequential treatment of enol silyl ethers with silver carboxylate-iodine (2:1) and then fluoride affords high yields of the corresponding α-acyloxy carbonyl compounds.Thus a wide range of variation is now possible for the acyloxy portion of the molecu

Full text of DOI:10.1021/jo00326a023

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