1-Benzyl-1-tert-butylhydrazine

Base Information

• Chemical Name: 1-Benzyl-1-tert-butylhydrazine
• CAS No.: 91215-73-5
• Molecular Formula: C11H18N2
• Molecular Weight: 178.274
• NSC Number: 109942
• DSSTox Substance ID: DTXSID20296569
• Wikidata: Q82037226
• Mol file: 91215-73-5.mol

Synonyms:91215-73-5;1-benzyl-1-tert-butylhydrazine;NSC109942;DTXSID20296569;NSC-109942

Chemical Property of 1-Benzyl-1-tert-butylhydrazine

Chemical Property:

• Vapor Pressure: 0.00334mmHg at 25°C
• Boiling Point: 282.5°Cat760mmHg
• Flash Point: 123.3°C
• Density: 0.975g/cm³
• XLogP3: 2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 178.146998583
• Heavy Atom Count: 13
• Complexity: 143

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)N(CC1=CC=CC=C1)N

Technology Process of 1-Benzyl-1-tert-butylhydrazine

There total 5 articles about 1-Benzyl-1-tert-butylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-benzyl-N-(tert-butyl)nitrous amide (20002-25-9) → N-Benzyl-N-tert-butyl-hydrazin (91215-73-5)

Guidance literature:

With acetic acid; zinc;

DOI:10.1021/jo01045a067

Reference yield:

N-tert-butylbenzylamine (3378-72-1) → N-Benzyl-N-tert-butyl-hydrazin (91215-73-5)

Guidance literature:

Multi-step reaction with 2 steps

1: HNO₂

2: Zn, AcOH

With cis-nitrous acid; acetic acid; zinc;

DOI:10.1021/jo01045a067

Reference yield:

N-benzylidene tert-butylamine (6852-58-0) → N-Benzyl-N-tert-butyl-hydrazin (91215-73-5)

Guidance literature:

Multi-step reaction with 3 steps

1: H₂ / Pt

2: HNO₂

3: Zn, AcOH

With hydrogen; cis-nitrous acid; acetic acid; zinc; platinum;

DOI:10.1021/jo01045a067

upstream raw materials:

N-benzyl-N-(tert-butyl)nitrous amide

N-benzylidene tert-butylamine

benzaldehyde

N-tert-butylbenzylamine

Downstream raw materials:

Benzophenon-N-benzyl-N-tert.-butyl-hydrazon