N-benzyl-N-tert-butylnitrous amide

Base Information

• Chemical Name: N-benzyl-N-tert-butylnitrous amide
• CAS No.: 20002-25-9
• Molecular Formula: C11H16 N2 O
• Molecular Weight: 192.261
• NSC Number: 130235
• DSSTox Substance ID: DTXSID90941978
• Wikidata: Q82918932
• Mol file: 20002-25-9.mol

Synonyms:20002-25-9;N-benzyl-N-tert-butylnitrous amide;NSC130235;SCHEMBL11691910;DTXSID90941978;NSC-130235

Chemical Property of N-benzyl-N-tert-butylnitrous amide

Chemical Property:

• Vapor Pressure: 0.000495mmHg at 25°C
• Boiling Point: 323.4°Cat760mmHg
• Flash Point: 149.4°C
• Density: 0.97g/cm³
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 192.126263138
• Heavy Atom Count: 14
• Complexity: 180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)N(CC1=CC=CC=C1)N=O

Technology Process of N-benzyl-N-tert-butylnitrous amide

There total 4 articles about N-benzyl-N-tert-butylnitrous amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N-tert-butylbenzylamine (3378-72-1) → N-benzyl-N-(tert-butyl)nitrous amide (20002-25-9)

Guidance literature:

With N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide; water; silica gel; sodium nitrite; In dichloromethane; at 20 ℃; for 0.05h; Reagent/catalyst;

DOI:10.2174/1570178611310030011

Reference yield:

N-benzylidene tert-butylamine (6852-58-0) → N-benzyl-N-(tert-butyl)nitrous amide (20002-25-9)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂ / Pt

2: HNO₂

With hydrogen; cis-nitrous acid; platinum;

DOI:10.1021/jo01045a067

Reference yield:

benzaldehyde (100-52-7) → N-benzyl-N-(tert-butyl)nitrous amide (20002-25-9)

Guidance literature:

Multi-step reaction with 3 steps

2: H₂ / Pt

3: HNO₂

With hydrogen; cis-nitrous acid; platinum;

DOI:10.1021/jo01045a067

upstream raw materials:

tetranitromethane

N,N-dibenzyl-2-methylpropan-2-amine

N-tert-butylbenzylamine

N-benzylidene tert-butylamine

Downstream raw materials:

N-tert-butylbenzylamine

N-Benzyl-N-tert-butyl-hydrazin

N,N-dibenzyl-2-methylpropan-2-amine

Benzophenon-N-benzyl-N-tert.-butyl-hydrazon