Carbon monoxide;dichloroplatinum;triphenylphosphanium

Base Information

• Chemical Name: Carbon monoxide;dichloroplatinum;triphenylphosphanium
• CAS No.: 19618-78-1
• Molecular Formula: C₁₉H₁₅Cl₂OPPt
• Molecular Weight: 556.287
• DSSTox Substance ID: DTXSID70422912
• Mol file: 19618-78-1.mol

Synonyms:NSC162932;19618-78-1;DTXSID70422912

Chemical Property of Carbon monoxide;dichloroplatinum;triphenylphosphanium

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 555.996377
• Heavy Atom Count: 24
• Complexity: 214

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pt]Cl

Technology Process of Carbon monoxide;dichloroplatinum;triphenylphosphanium

There total 13 articles about Carbon monoxide;dichloroplatinum;triphenylphosphanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

carbon monoxide (201230-82-2) + cis-[PtCl2(NCEt)(PPh3)] (1354395-23-5) → cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1)

Guidance literature:

With propiononitrile; at 20 ℃; for 24h; under 760.051 Torr; Inert atmosphere;

DOI:10.1016/j.ica.2012.10.038

Reference yield:

trans-dichloro-((Ph3)phosphine)(carbonyl)platinum(II) (19618-78-1,73347-20-3,22585-09-7) → bis(triphenylphosphine)platinum(II) dichloride (10199-34-5,14056-88-3,15604-36-1) + cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1)

Guidance literature:

With catalyst: triphenylphosphine;

DOI:10.1016/S0020-1693(00)90938-1

Reference yield:

{PtCl2(PPh3)}2 + carbon monoxide (201230-82-2) → trans-dichloro-((Ph3)phosphine)(carbonyl)platinum(II) (19618-78-1,73347-20-3,22585-09-7)

Guidance literature:

In benzene; Pt compound in CH2Cl2 cooled to -40°C, CO bubbled through the soln. for 5 min; cooled to -50°C, solvent removed by evacuating at this temp.;

DOI:10.1039/DT9800001988

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

trans-dichloro-((Ph₃)phosphine)(carbonyl)platinum(II)

cis-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)

carbon monoxide

Downstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾

trans-[PtCl(SnCl₃)2(P(C₆H₅)3)]^(1-)

Fe₂Pt(CO)9(P(C₆H₅)3)

Refernces

• 1、 Dell'Amico, Daniela Belli,Broglia, Claudio,Labella, Luca,Marchetti, Fabio,Mendola, Daniele,Samaritani, Simona. "Platinum(II) complexes containing unsaturated ligands. Nucleophilic substitution versus nucleophilic attack to ligand: A stereochemistry driven outcome". . p. 181 - 188. Retrieved 2013/07/05.
• 2、 Anderson,Clark,Davies. "Reactivity of platinum diolefin complexes. Roles of trans influence and chelate effect". . p. 1636 - 1639. Retrieved 2008/10/08.