BenzeneMethanaMine, N,N,3-triMethyl-

Base Information

• Chemical Name: BenzeneMethanaMine, N,N,3-triMethyl-
• CAS No.: 23879-32-5
• Molecular Formula: C10H15N
• Molecular Weight: 149.236
• Mol file: 23879-32-5.mol

Synonyms:N,N,3-TRIMETHYL-BENZENEMETHANAMINE;3-methyldimethylbenzylamine;N,N-dimethyl(3-methylbenzyl)amine;N,N-dimethyl-1-m-tolylmethanamine;9-AZABICYCLO[3.3.1]NONAN-3-AMINE, 54-METHYL-;N,N-dimethyl-3-methylbenzylamine;dimethyl-(3-methyl-benzyl)-amine;N,N,3-trimethylbenzylamine;

Chemical Property of BenzeneMethanaMine, N,N,3-triMethyl-

Chemical Property:

• PSA: 3.24000
• LogP: 2.05660

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BenzeneMethanaMine, N,N,3-triMethyl-

There total 15 articles about BenzeneMethanaMine, N,N,3-triMethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

methanol (67-56-1) + 3-methyl-benzenemethanamine (100-81-2) → N,N,3-trimethylbenzylamine (23879-32-5)

Guidance literature:

With (C₅(CH₃)5)IrCl₂(1,3-diisoptopylimidazole); potassium carbonate; at 70 ℃; for 40h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1055/s-0037-1610252

Reference yield: 87.0%

methanol (67-56-1) + 1-(azidomethyl)-3-methylbenzene (126799-82-4) → N,N,3-trimethylbenzylamine (23879-32-5) + N-methyl-1-(m-tolyl)methanamine (39180-84-2)

Guidance literature:

With trans-RuCl(phenpyra-Me)(PPh₃)₂PF₆; sodium hydroxide; at 125 ℃; for 24h; Sealed tube; Inert atmosphere; Glovebox;

DOI:10.1039/c8gc00863a

Reference yield: 81.0%

methanol (67-56-1) + 3-Methylbenzonitrile (620-22-4) → N,N,3-trimethylbenzylamine (23879-32-5)

Guidance literature:

With C₅₄H₄₃ClN₃P₂Ru⁽¹⁺⁾*F₆P^(1-); potassium tert-butylate; at 140 ℃; for 24h;

DOI:10.1021/acscatal.8b00021

upstream raw materials:

hexamethylenetetramine

1-bromomethyl-3-methyl-benzene

formaldehyd

3-methyl-benzenemethanamine

Downstream raw materials:

3,N,N-Trimethyl-2-neopentylbenzylamin

Hg(C₆H₃(CH₃)-5-CH₂NMe₂-2)2

3-methylbenzyldimethylamine borane

N-(tert-butoxycarbonylmethyl)-N,N-dimethyl-N-(3-methylbenzyl)ammonium bromide