Trimethyl(2,3,5,6-tetrafluorophenyl)stannane

Base Information

Chemical Name:Trimethyl(2,3,5,6-tetrafluorophenyl)stannane
CAS No.:23653-74-9
Molecular Formula:C9H10F4Sn
Molecular Weight:312.882
Hs Code.:2931900090
Mol file:23653-74-9.mol

Synonyms:Trimethyl(2,3,5,6-tetrafluorophenyl)stannane

Suppliers and Price of Trimethyl(2,3,5,6-tetrafluorophenyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Trimethyl(2,3,5,6-tetrafluorophenyl)stannane

Chemical Property:

PSA：0.00000
LogP:2.78820

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Trimethyl(2,3,5,6-tetrafluorophenyl)stannane

There total 2 articles about Trimethyl(2,3,5,6-tetrafluorophenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 1559-88-2
1-bromo-2,3,5,6-tetrafluorobenzene

: 1066-45-1
trimethyltin(IV)chloride

: 23653-74-9
trimethyl(2,3,5,6-tetrafluorophenyl)tin

Guidance literature:: With butyllithium; In tetrahydrofuran; hexane; addn. of Me3SnCl in ether or THF to phenyllithium reagent (prepd. from p-HC6F4Br and BuLi in ether or THF and hexane); stirring (-78°C, 2-3 h) warming to room temp.; hydrolysis with aq. NH4Cl; extn. (ether or CH2Cl2), drying (MgSO4), evapn., distn. (vac.); elem. anal.;
DOI:10.1016/0022-328X(89)85436-1

Reference yield:

: 327-54-8
1,2,4,5-Tetrafluorobenzene

: 1066-45-1
trimethyltin(IV)chloride

: 23653-74-9
trimethyl(2,3,5,6-tetrafluorophenyl)tin

Guidance literature:: With n-butyllithium; In diethyl ether; at -78 to 25°C;;
DOI:10.1016/S0022-328X(00)87755-4

Reference yield: 51.0%

: 12152-26-0
dichloro(2,3,5,6-η4-bicyclo{2.2.1}hepta-2,5-dien)platinum(II)

: 23653-74-9
trimethyl(2,3,5,6-tetrafluorophenyl)tin

: chloro(η4-norbornadiene)(2,3,5,6-tetrafluorophenyl)platinum(II)

: (η4-norbornadiene)bis(2,3,5,6-tetrafluorophenyl)platinum(II)

: 1066-45-1
trimethyltin(IV)chloride

Guidance literature:: In dichloromethane; under nitrogen, 41°C, 96 h,; TLC monitoring, solvent removed (vac.); residue washed (warm petroleum ether; chromy. (silica, CH2Cl2/petroleum ether 2/1, v/v), crystn. from eluant solvent, elem. anal.;
DOI:10.1016/0022-328X(89)85436-1