4-[(METHOXYBENZYLIDENE)AMINO]STILBENE

Base Information

• Chemical Name: 4-[(METHOXYBENZYLIDENE)AMINO]STILBENE
• CAS No.: 322413-12-7
• Molecular Formula: C22H19NO
• Molecular Weight: 313.39
• Mol file: 322413-12-7.mol

Synonyms:4-(P-ANISALAMINO)STILBENE;4-[(P-ANISYLIDENE)AMINO]STILBENE;4-[(METHOXYBENZYLIDENE)AMINO]STILBENE;4-(4-Methoxybenzylideneamino)stilbene;N-(4-Methoxybenzylidene)-4-styrylaniline;4-(p-Anisalamino)stilbene 4-[(p-Anisylidene)amino]stilbene

Chemical Property of 4-[(METHOXYBENZYLIDENE)AMINO]STILBENE

Chemical Property:

• Boiling Point: 488.0±34.0 °C(Predicted)
• PKA: 4.04±0.50(Predicted)
• Density: 1.00±0.1 g/cm3(Predicted)
• Solubility.: almost transparency in hot Toluene

Purity/Quality:

97% ^*data from raw suppliers

4-[(Methoxybenzylidene)amino]stilbene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-[(METHOXYBENZYLIDENE)AMINO]STILBENE

There total 4 articles about 4-[(METHOXYBENZYLIDENE)AMINO]STILBENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-4-nitrostilbene (1694-20-8) → N-(4-methoxybenzylidene)-4-((E)-styryl)aniline (322413-12-7)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride; tin(II) chloride dihdyrate / ethanol; water / 7 h / 20 °C / Reflux

2: ethanol / 1 h / 80 °C

With hydrogenchloride; tin(II) chloride dihdyrate; In ethanol; water;

DOI:10.1002/poc.3032

Reference yield:

4-nitrobenzyl chloride (100-14-1) → N-(4-methoxybenzylidene)-4-((E)-styryl)aniline (322413-12-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 5 h / 140 °C

2: sodium hydride / tetrahydrofuran / 0.5 h / 50 °C / Inert atmosphere

3: hydrogenchloride; tin(II) chloride dihdyrate / ethanol; water / 7 h / 20 °C / Reflux

4: ethanol / 1 h / 80 °C

With hydrogenchloride; tin(II) chloride dihdyrate; sodium hydride; In tetrahydrofuran; ethanol; water;

DOI:10.1002/poc.3032

Reference yield:

diethyl p-nitrobenzylphosphonate (2609-49-6) → N-(4-methoxybenzylidene)-4-((E)-styryl)aniline (322413-12-7)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium hydride / tetrahydrofuran / 0.5 h / 50 °C / Inert atmosphere

2: hydrogenchloride; tin(II) chloride dihdyrate / ethanol; water / 7 h / 20 °C / Reflux

3: ethanol / 1 h / 80 °C

With hydrogenchloride; tin(II) chloride dihdyrate; sodium hydride; In tetrahydrofuran; ethanol; water;

DOI:10.1002/poc.3032

upstream raw materials:

trans-4-nitrostilbene

p-amino-trans-stilbene

4-methoxy-benzaldehyde

4-nitrobenzyl chloride