2-BROMOINDAN

Base Information

• Chemical Name: 2-BROMOINDAN
• CAS No.: 1762-39-6
• Molecular Formula: C9H9Br
• Molecular Weight: 364.49
• Mol file: 1762-39-6.mol

Synonyms:2-BROMOINDAN;2-BROMO-2,3-DIHYDRO-1H-INDENE;2-BroMo-2,3-dihydroindene;β-BroMoindane;1H-Indene, 2-broMo-2,3-dihydro-

Chemical Property of 2-BROMOINDAN

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-BROMOINDAN

There total 8 articles about 2-BROMOINDAN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

4,4′-bis(α-styrene)-2,2′-bypiridine (1762-40-9) → 4,4′-diphenylethyl-2,2′-bipyridine (1762-39-6)

Guidance literature:

With palladium 10% on activated carbon; hydrazine hydrate; In ethanol; for 3h; Reflux; Inert atmosphere;

DOI:10.1039/c6nj00213g

Reference yield: 35.0%

benzyl bromide (100-39-0) + 4,4’-bis[(trimethylsilyl)methyl]-2,2’-bipyridine (199282-52-5) → 4,4′-diphenylethyl-2,2′-bipyridine (1762-39-6)

Guidance literature:

With cesium fluoride; In N,N-dimethyl-formamide; at 25 ℃; for 2h;

DOI:10.1021/jo971685x

Reference yield: 7.0%

4,4'-dimethyl-2,2'-bipyridines (1134-35-6) + benzyl chloride (100-44-7) → 4,4'-bis(1-benzylphenethyl)-2,2'-bipyridine (106376-87-8) + 4,4′-diphenylethyl-2,2′-bipyridine (1762-39-6)

Guidance literature:

With sodium amide;

DOI:10.1021/jo00380a008

upstream raw materials:

4,4'-dimethyl-2,2'-bipyridines

benzyl chloride

benzyl bromide

4,4’-bis[(trimethylsilyl)methyl]-2,2’-bipyridine

Downstream raw materials:

[iridium bis(7,8-benzoquinoline)(4,4-bis(2-phenylethyl)-2,2'-bipyridine)]hexafluorophosphate

2,11-bis(4-sulfonatophenethyl)-6,7-dihydrodipyrido<1,2-a:2',1'-c>pyrazinium

4,4'-bis(4-sulfonatophenethyl)-2,2'-bipyridinium

2,11-diphenethyl-6,7-dihydrodipyrido<1,2-a:2',1'-c>pyrazinium dibromide